Unit 4.2 Resonance, Shapes, and Giant Structures

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Resonance Structures

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18 Terms

1

Resonance Structures

Structures that represent different possible arrangements of electrons in a molecule, ion, or solid metal, where the electrons are delocalized and not permanently associated with one atom or covalent bond.

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2

Nitrate (V) Ion

A molecule with 1 double bond and 2 single bonds, which has 3 possible resonance structures where the double bond moves around and is with each of the three oxygens.

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3

Resonance Hybrid

The actual structure of a molecule that is a combination or intermediate between multiple resonance structures, where the electron density is spread evenly between atoms and the bond lengths are between a single and a double bond.

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4

Valence Shell Electron Pair Repulsion (VSEPR) Theory

A theory that predicts molecular shape and bond angles based on the concept that electron pairs, both bonding and lone pairs, arrange themselves as far apart in space as possible.

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5

Steric Number (SN)

The sum of the number of atoms and lone pairs around the central atom in a molecule, which determines the molecular shape according to VSEPR theory.

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6

Linear

A molecular geometry where the central atom is bonded to two other atoms, resulting in a bond angle of 180°.

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7

Trigonal Planar

A molecular shape where the central atom is bonded to three other atoms, resulting in a bond angle of 120°.

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8

Bent Linear

A molecular geometry where the central atom is bonded to two other atoms and has one lone pair, resulting in a bond angle slightly less than 120°.

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9

Tetrahedral

A molecular geometry where the central atom is bonded to four other atoms, resulting in a bond angle of 109.5°.

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10

Trigonal Pyramidal

A molecular shape where the central atom is bonded to three other atoms and has one lone pair, resulting in a bond angle slightly less than 109.5°.

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11

Bent

A molecular geometry where the central atom is bonded to two other atoms and has two lone pairs, resulting in a bond angle slightly less than 109.5°.

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12

Molecular Polarity

The overall polarity of a molecule, determined by the arrangement of polar bonds and whether their dipole moments cancel each other out.

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13

Giant Covalent Structures

Covalent lattices where the bonds between atoms continue forever, forming a large lattice with no separate molecules.

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14

Allotrope

Different atomic or molecular arrangements of the same element in the same physical state.

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15

Diamond

A giant lattice of carbon atoms, where each carbon is covalently bonded to four others in a tetrahedral geometry, resulting in a very hard substance.

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16

Graphite

A layered structure of carbon atoms, where each carbon is bonded to three others in a hexagonal pattern, and the spare electron is delocalized between the layers.

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17

Buckminsterfullerene

A molecule containing 60 carbon atoms, where each atom is bonded to three others by single covalent bonds and the fourth electron is delocalized, allowing for semi-conducting properties.

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18

Graphene

A single layer of carbon atoms bonded in a repeating hexagonal pattern, considered a 2D material due to its thinness and has unique properties such as strength, flexibility, and transparency.

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