Isomers

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26 Terms

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2 main groups of isomers

constitutional (structural) and stereoisomers

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2 types of stereoisomers (spatial isomers)

enantiomers and diastereomers

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2 types of diastereomers

Conformers and Cis/trans isomers

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functional group

determines the behavior of organic compounds

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hydrocarbons

hydrogen + carbon atoms

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alkanes

all C - C single bonds

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Alkenes

one or more C double bond C

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alkynes

one or more C triple bond C

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alkanes name

prefix + ane

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alkenes name

prefix + ene

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Alkynes name

prefix + yne

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Alkanes are

saturated hydrocarbon

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alkenes are

unsaturated hydrocarbons

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alkynes are

unsaturated hydrocarbons

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saturated hydrocarbons (alkanes)

have the max number of H per C in the chain

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unsaturated hydrocarbons

have less than max number of H per C

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hydrogenation

process of combining with H2 to form alkanes

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isomers

same chemical formula, different 3D structures

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constitutional isomers (structural)

same formula but different connectivity of atoms

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cis unsaturated fats

low density, kinks

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saturated fats

dense, no kinks

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trans - unsaturated fats

no kinks, highest density, stacking is stronger by double bonded C groups

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enatiomers

when an object is chiral, mirror image and non-superimposable

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Conformers

have sigma (single) bonds so it can rotate

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cis isomers

cut along long bond length, if atoms are on the same side = cis

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trans isomers

cut along bond length, atoms are on different sides = trans