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2 main groups of isomers
constitutional (structural) and stereoisomers
2 types of stereoisomers (spatial isomers)
enantiomers and diastereomers
2 types of diastereomers
Conformers and Cis/trans isomers
functional group
determines the behavior of organic compounds
hydrocarbons
hydrogen + carbon atoms
alkanes
all C - C single bonds
Alkenes
one or more C double bond C
alkynes
one or more C triple bond C
alkanes name
prefix + ane
alkenes name
prefix + ene
Alkynes name
prefix + yne
Alkanes are
saturated hydrocarbon
alkenes are
unsaturated hydrocarbons
alkynes are
unsaturated hydrocarbons
saturated hydrocarbons (alkanes)
have the max number of H per C in the chain
unsaturated hydrocarbons
have less than max number of H per C
hydrogenation
process of combining with H2 to form alkanes
isomers
same chemical formula, different 3D structures
constitutional isomers (structural)
same formula but different connectivity of atoms
cis unsaturated fats
low density, kinks
saturated fats
dense, no kinks
trans - unsaturated fats
no kinks, highest density, stacking is stronger by double bonded C groups
enatiomers
when an object is chiral, mirror image and non-superimposable
Conformers
have sigma (single) bonds so it can rotate
cis isomers
cut along long bond length, if atoms are on the same side = cis
trans isomers
cut along bond length, atoms are on different sides = trans