Chem II Exam 3

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28 Terms

1

BAAD meaning

Bases accept, acids donate

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2

[H3O][OH]=kw=

1 × 10^-14

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3

An amphoteric species can be

an acid or a base

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4

Brønsted-Lowry bases accept ? and Brønsted-Lowry acids donate ?

protons

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5

pH for H+ formula

-logH+

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6

pOH for OH- formula

-logOH-

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7

pH + pOH=

14

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8

Higher Ka value means

stronger acid

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9

Lower Ka value means

weaker acid

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10

Does a high Ka have a lower or higher pH?

lower

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11

A buffer forms when a

conjugate weak acid/weak base pair are mixed together.

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12

Formula to calculate pH

pH=pKa+log[base]/[acid]

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13

Spontaneous process

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14

A negative ΔS indicates that the system has become

more ordered

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15

ΔS formula

nΔS products-ΔS reactants

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16

If both ΔH and ΔS are positive, then T must be

large

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17

Entropy is positive when

the degrees of freedom of the system increases

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18

G formula

G= H-TS

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19

If a chemical reaction has a negative ∆H and a negative ∆S, then

it will be spontaneous at low temperatures and non-spontaneous at high temperatures.

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20

A reaction which is endothermic and has an overall increase in entropy is

spontaneous only at high T

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21

If a chemical reaction has a positive ∆H and a negative ∆S, then

it will be non-spontaneous at all temperatures.

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22

A reaction will be spontaneous at all temperatures if

∆H is negative and ∆S is positive

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23

salt of a weak base and a strong acid have what type of pH

acidic

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24

salt of a weak acid and a strong base have what type of pH

basic

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25

larger kb means

stronger base

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26

smaller kb means

weaker base

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27

amphoteric

capable of acting as an acid or base depending on what they are reacting with

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28

amphiprotic

substance that can accept and donate hydrogen ions

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