3.1.3 - Lipids

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Triglyceride structure

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Triglyceride structure

1 glycerol + 3 fatty acid

<p><strong>1 glycerol</strong> + <strong>3 fatty acid</strong></p>
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2

Fatty acid molecules

  • Have ‘tails’ made of hydrocarbons

  • Tails ‘hydrophobic’ (repel water)

    • → lipids insoluble in water

  • All fatty acids have same basic structure, but hydrocarbon tail varies

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3

Basic structure of fatty acid

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4

What bond forms between glycerol + fatty acid?

Ester bond

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5

What reaction occurs during formation of triglycerides?

Condensation reaction

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6

Formation of triglycerides

  • Ester bond forms between each fatty acid and the gycerol molecule

    • Each time, water molecule is released

  • 3x condensation reactions

<ul><li><p><strong>Ester bond</strong> forms between each fatty acid and the gycerol molecule</p><ul><li><p>Each time, <strong>water </strong>molecule is <strong>released</strong></p></li></ul></li><li><p><strong>3x condensation reactions</strong></p></li></ul><p></p>
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7

Saturated fatty acid

No double bonds between C atoms (in hydrocarbon tail/R group)

<p><strong>No double bonds</strong> between <strong>C atoms</strong> (in <strong>hydrocarbon tail/R group</strong>)</p>
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8

Unsaturated fatty acid

1+ double bond between C atoms

→ causes kinks in chain

<p><strong>1+ double bond</strong> between <strong>C atoms</strong></p><p>→ causes <strong>kinks </strong>in chain</p>
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9

Phospholipids

  • Found in cell membrane

  • 1 fatty acid replaced by phosphate group

  • Phosphate group hydrophilic (attracts water)

<ul><li><p>Found in<strong> cell membrane</strong></p></li><li><p>1 fatty acid replaced by<strong> phosphate group</strong></p></li><li><p>Phosphate group <strong>hydrophilic</strong> (attracts water)</p></li></ul><p></p>
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10

Structure + function of triglycerides

Energy storage molecules

  • Long hydrocarbon tails contains lots of chemical energy

    • → lots of energy released when they’re broken down

    • Lipids have 2x energy per gram than carbohydrates

  • Insoluble

    • don’t affect water potential and cause water to enter by osmosis

    • Triglycerides stay together as insoluble droplets in cells

      • → fatty acid tails hydrophobic so face inwards, shielded from water

<p><strong>Energy storage molecules</strong></p><ul><li><p><strong>Long hydrocarbon tails </strong>contains lots of <strong>chemical energy</strong></p><ul><li><p>→ lots of energy <strong>released</strong> when they’re <strong>broken down</strong></p></li><li><p>Lipids have <strong>2x </strong>energy per gram than carbohydrates </p></li></ul></li><li><p><strong>Insoluble</strong></p><ul><li><p>→ <strong>don’t affect water potential</strong> and cause water to enter by <strong>osmosis</strong></p></li><li><p>Triglycerides stay together as <strong>insoluble droplets </strong>in cells</p><ul><li><p>→ fatty acid tails <strong>hydrophobic</strong> so <strong>face inwards</strong>, shielded from water </p></li></ul></li></ul></li></ul><p></p>
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11

Structure + function of phospholipids

Make up bilayer of cell membranes (which control what enters/leaves cell)

  • Hydrophilic heads + hydrophobic tails

    • → form double layer with heads facing out towards water

  • Centre of bilayer hydrophobic

    • → water-soluble substances can’t pass through easily

      • → membrane is barrier to those substances

<p>Make up <strong>bilayer </strong>of <strong>cell membranes </strong>(which <strong>control</strong> what <strong>enters/leaves </strong>cell)</p><ul><li><p><strong>Hydrophilic heads</strong> + <strong>hydrophobic tails</strong></p><ul><li><p>→ form <strong>double layer </strong>with heads facing <strong>out </strong>towards water</p></li></ul></li><li><p><strong>Centre </strong>of bilayer <strong>hydrophobic</strong></p><ul><li><p>→ water-soluble substances <strong>can’t </strong>pass through easily</p><ul><li><p>→ membrane is<strong> barrier</strong> to those substances</p></li></ul></li></ul></li></ul><p></p>
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12

Name of test for lipids

Emulsion test

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Test for lipids

  1. Shake test substance with ethanol for 1min so it dissolves, then pour solution into water

  2. Any lipid shows up as milky emulsion

  3. More lipid = more noticeable milky colour

<ol><li><p><strong>Shake </strong>test substance with <strong>ethanol </strong>for 1min so it dissolves, then <strong>pour </strong>solution into <strong>water</strong></p></li><li><p>Any lipid shows up as <strong>milky emulsion</strong></p></li><li><p>More lipid = more noticeable milky colour</p></li></ol><p></p>
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