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hybridisation
a theory that is used to explain certain molecular geometries that would not have been possible otherwise
sp3 hybridisation
refers to the mixing character of one 2s-orbital and three 2p-orbitals to create 4 hybrid orbitals with similar characteristics
all 4 orbitals are delocalised and can house 2 electrons
sp hybridisation
One of the 2s electrons is first promoted to the empty 2p orbital
Now the hybridisation takes place only with occupied orbitals, and the result is a pair of sp hybrid orbitals. The two remaining p orbitals do not hybridise and remain unoccupied
linear in shape
sp2 hybridisation
First, a paired 2s electron is promoted to the empty 2py orbital
This is followed by hybridisation of the three occupied orbitals to form a set of three sp2 hybrids, leaving the 2pz orbital unhybridised
trigonal planar in shape
pi bond
occurs when two atomic orbitals overlap side-to-side
This type of bond is weaker than a sigma bond
double bond
consists of 1 sigma and 1 pi bond
triple bond
consists of 1 sigma and 2 pi bonds