3.2-3.4 ionic, metallic and covalent bonding

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36 Terms

1
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Define ionic bonding

Electrostatic attraction between oppositely charged ions

2
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Describe ionic bonding

Transfer of electrons from a metallic element to a non-metallic element

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Define metallic bonding

The electrostatic forces of attraction between the positive metal ions and the sea of delocalised electrons

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Define covalent bonding

Electrostatic forces of attraction between the shared pair of electrons and positively charged nuclei

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Describe the covalent bonding in H2

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Describe the covalent bonding in oxygen

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Describe the covalent bonding in Nitrogen

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Describe the covalent bonding in Chlorine

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Describe the covalent bonding in HCl

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Describe the covalent bonding in CO2

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Describe the covalent bonding in Ammonia

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Describe the covalent bonding in Methane

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Describe the covalent bonding in Ethane

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Describe the covalent bonding in ethene

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What is special about covalent bonding in period 3?

Elements in period 3 can expand their octet

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Describe the covalent bonding in SO2

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Describe the covalent bonding in PCl5

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Describe the covalent bonding in SF6

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Define coordinate bonding

When both electrons in the shared pair come from the same atom

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Describe the reaction between HCl and ammonia gases

NH3 + HCl → NH4Cl

<p>NH3 + HCl → NH4Cl</p>
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Describe the reaction of dissolving HCl in water

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22
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Describe the covalent bonding in Al2Cl6

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Describe the covalent bonding in CO

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Describe the covalent bonding in HNO3

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What is a Sigma bond?

Direct overlap of orbitals between the bonding atoms

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What is a pi bond?

Formed by the sideways overlap of adjacent p orbitals above and below the sigma bond

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How to sigma bonds form in H2

S orbitals of 2 H atoms overlap to form a sigma bond

<p>S orbitals of 2 H atoms overlap to form a sigma bond</p>
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How do sigma bonds form in C2H6

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How do sigma and pi bonds form in C2H4

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How do sigma and pi bonds form in HCN

  • Hydrogen cyanide contains a triple bond

  • One σ bond is formed between the H and C atom (overlap of an sp C hybridised orbital with the 1s H orbital)

  • A second σ bond is formed between the C and N atom (overlap of an sp C hybridised orbital with an sp orbital of N)

  • The remaining two sets of p orbitals of nitrogen and carbon will overlap to form two π bonds at right angles to each other

<ul><li><p>Hydrogen cyanide contains a <strong>triple bond</strong></p></li><li><p>One σ bond is formed between the H and C atom (<strong>overlap of an sp C hybridised orbital with the 1s H orbital)</strong></p></li><li><p>A second σ bond is formed between the C and N atom (<strong>overlap of an sp C hybridised orbital with an sp orbital of N)</strong></p></li><li><p>The remaining <strong>two sets</strong> of p orbitals of <strong>nitrogen and carbon </strong>will overlap to form <strong>two</strong> <strong>π bonds </strong>at right angles to each other</p></li></ul><p></p>
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How do sigma and pi bonds form in N2

  • Nitrogen contains a triple bond

  • The triple bond is formed from the overlap of the sp orbitals on each N to form a σ bond and the overlap of two sets of p orbitals on the nitrogen atoms to form two π bonds

  • These π bonds are at right angles to each other

<ul><li><p>Nitrogen contains a <strong>triple bond</strong></p></li><li><p>The triple bond is formed from the overlap of the sp orbitals on each N to form a <strong>σ bond </strong>and the overlap of <strong>two sets</strong> of p orbitals on the nitrogen atoms to form <strong>two π bonds</strong></p></li><li><p>These π bonds are at <strong>right angles to each other</strong></p></li></ul><p></p>
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Define bond energy

The energy required to break one mole of a particular covalent bond in the gaseous state

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Define bond length

Intermolecular distance of 2 covalently bonded atoms

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What is sp3 hybridisation?

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What is sp2 hybridisation?

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What is sp hybridisation?