AP Chemistry Chp 5: Aqueous Solutions

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For an atom in its elemental form, the oxidation number is always ___

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1

For an atom in its elemental form, the oxidation number is always ___

0

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2

For any monatomic ion, the oxidation number equals the ___ on the ion

Charge

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3

Nonmetals usually have ___ oxidation numbers, but not always

Negative

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4

The oxidation number of oxygen is usually ___ in both ionic and molecular compounds

-2

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5

In peroxides, which contain the O2^2- ion, oxygen has an oxidation number of ___

-1

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6

The oxidation number of hydrogen is ___ when bonded to nonmetals and ___ when bonded to metals

+1, -1

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7

The oxidation number of fluorine is ___ in all compounds.

-1

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8

The halogens have an oxidation number of ___ in most binary compounds. Exception: when halogens are combined with oxygen, as in oxyanions, they have ___ oxidation states

-1, positive

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9

General pattern for redox reactions

A + BX ---> AX +B

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10

Other names for redox / oxidation-reduction reactions

Single-replacement, displacement

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11

A list of metals arranged in order of decreasing ease of oxidation; also includes hydrogen.

Activity Series

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12

In the activity series, the elements at the ___ are the most easily oxidized; referred to as active metals.

Top

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13

In the activity series, the elements at the ___ have the lowest reactivity; referred to as noble metals.

Bottom

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14

Any metals on the activity list can oxidize a metal listed ___ it.

Below

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15

The amount of solute dissolved in a given quantity of solvent or quantity of solution

Concentration

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16

Molarity is the number of ___ of solute in a ___ of solution

Moles, liter

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17

When an ___ compound dissolves, the relative ___ of the ions introduced in the solution depend on the ___ formula of the compound.

Ionic, concentrations, chemical

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18

___ contains three quantities -- molarity, moles ___, liters ___. So if we know any two of these we can calculate the third.

Molarity, solute, solution

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19

Solutions that are used routinely in the laboratory are often purchased or prepared in concentrated form, called ___ ___.

Stock solutions

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20

When a ___ is added to dilute a solution, the number of moles of ___ remains unchanged.

Solvent, solute

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21

When a ___ is added to dilute a solution, the number of moles of ___ remains unchanged.

Solvent, solute

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22

To calculate the volume needed to make a diluted solution, we use the equation ...

MconcVconc = MdilVdil

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23

The process of reacting a solution of unknown concentration with one of known concentration

Titration

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24

___ can be conducted with acid-base, precipitation, or redox reactions

Titrations

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25

In order to titrate, you need a way to determine when the ___ ___ has been reached

Equivalence point

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26

To determine the equivalence point for acid-base titrations, dyes known as acid-base ___ are used.

Indicators

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27

The ___ change signals the ___ point, which usually coincides very nearly with the equivalence point.

Color, end

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28

A homogenous mixture of two or more substances

Solution

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29

The substance present in the greatest quantity

Solvent

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30

The other substances present in the solution

Solute

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31

Water itself is a poor conductor of ___, but the presence of ___ causes aqueous solutions to become good conductors

Electricity, ions

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32

___ carry electrical charge from one ___ to the other, completing the electrical circuit

Ions, electrode

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33

A substance whose aqueous solutions contain ions

Electrolyte

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34

A substance that does not form ions in solutions

Nonelectrolyte

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35

What compounds are considered electrolytes?

All covalent/ molecular compounds except for acids

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36

___ is a very effective solvent for ionic compounds due to its polar nature. The partially positive H is attracted to the ___, and the partially negative O is attracted to the ___

Water, anion, cation

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37

When the ions become surrounded by H2O molecules, the ions are said to be

Solvated

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38

When a ___ compound dissolves in water, such as CH3OH, the solution usually contains intact ___ dispersed throughout the solution. Without any ____ particles, the solution is unable to conduct electricity.

Molecular, molecules, charged

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39

Solutes that exist in solution completely or nearly completely as ions: consist of all soluble ionic compounds and a few molecular compounds

Strong electrolyte

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40

Solutes that exist in solution mostly in the form of molecules with only a small fraction in the form of ions

Weak electrolyte

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41

Chemists use a ___ arrow for weak electrolytes and a ___ arrow for strong electrolytes.

Single, double

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42

Reactions that result in the formation of an insoluble product are known as ___ reactions

Precipitation

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43

Precipitation reactions occur when certain pairs of ____ charged ions attract each other so strongly that they form an insoluble ionic ___.

Oppositely, solid

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44

7 strong acids are

HCl, HClO3, HClO4, HI, HBr, HNO3, H2SO4

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45

Double-replacement reactions follow the general formula:

AX + BY ---> AY + BX

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46

An equation written with all soluble strong electrolytes shown as ions

Complete ionic equation

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47

Ions that appear in identical forms among both the reactants and products of a complete ionic equation. They are present but play no direct role in the reaction.

Spectator ions

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48

When spectator ions are omitted we are left with the

Net ionic equation

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49

In a net ionic equation, ___ should be conserved. If every ion is a ___ then no reaction occurs!

Charge, spectator

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50

___ reactions are when H^+ and OH^- ions come together to form H2O

Neutralization

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51

Reactions where electrons are transferred between reactants.

Oxidation-reduction or redox reactions

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52

The conversion of a metal into a metal compound by a reaction between the metal and some other substance in its environment.

Corrosion

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53

When an atom, ion, or molecule has become more positively charged, we say that it has been ___.

oxidized

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54

When an atom, ion, or molecule has become more negatively charged, we say that it has been ___.

Reduced

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55

The loss of electrons

Oxidation

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56

The gain of electrons

Reduction

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57

The oxidation of one substance is always accompanied by the ___ of another as ___ are transferred between them

Reduction, electrons

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58

Oxidation occurs when there is an ___ in oxidation number; reduction occurs when there is a ___ in oxidation number

Increase, decrease

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