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22 Terms

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Ionic Bonding

Found in compounds composed of metallic and nonmetallic elements; involves atoms at the extremes of the periodic table.

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Covalent Bonding

Found in materials with small differences in electronegativity (near each other in the periodic table); atoms achieve stable electron configurations by sharing electrons.

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Metallic Bonding

Found in metals and their alloys; valence electrons are delocalized, forming a 'sea of electrons'.

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Van der Waals Forces

Weak electric forces that attract neutral molecules, present in gases, liquefied/solidified gases, and most organic liquids/solids.

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Crystalline Structure

The ordered arrangement of atoms, molecules, or ions in a solid; characterized by repeating units called unit cells.

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Atomic Packing Factor (APF)

A measure of how efficiently atoms are packed within a unit cell, defined as the ratio of the total volume of atoms in a unit cell to the volume of the unit cell.

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Face Centered Cubic (FCC)

Atoms located at each of the 8 corners and the centers of each of the 6 faces; atomic packing factor of 0.74.

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Body Centered Cubic (BCC)

Atoms located at each of the 8 corners and the center of the cubic cell; less dense than FCC with an atomic packing factor of 0.68.

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Hexagonal Close Packing (HCP)

BA packing arrangement composed of two hexagons of 6 atoms each and additional atoms in between; has an atomic packing factor of 0.74.

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Simple Cubic (SC)

The simplest atomic arrangement, only containing atoms at each corner of the unit cell; least dense with an atomic packing factor of 0.52.

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Point Defects

Localized disruptions in crystalline materials, which include vacancies, interstitials, impurities, and Frenkel and Schottky defects.

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Elastic Modulus

A measure of a material’s stiffness, reflecting its resistance to elastic deformation under stress.

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Fracture Toughness

A measure of a material's ability to resist crack propagation and indicates greater energy absorption before fracturing.

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Thermal Expansion

The increase in size or volume of a material as its temperature rises; crucial for materials that undergo temperature changes.

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Dielectric Properties

The ability of a material to store electrical energy in an electric field, characterized by dielectric constant and dielectric loss.

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Hydroplasticity

The property of clay that allows it to become plastic and pliable when mixed with water.

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Refractory Ceramics

Materials designed to withstand high temperatures without melting or decomposing, used for thermal insulation in severe environments.

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Abrasive Ceramics

Materials used for wearing, grinding, or cutting softer materials, requiring properties like hardness and wear resistance.

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X-Ray Diffraction

A technique used to study the atomic structure of materials by analyzing the pattern of scattered X-rays.

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TTT Diagrams

Charts that show the phase transformations of materials at different temperatures and times.

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Thermal Shock

The stress and potential cracking of a material undergoing rapid temperature changes.

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Non-Centrosymmetric Crystals

Structures required to exhibit piezoelectricity, allowing them to generate electric charge under mechanical stress.