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Man made solid objects formed by baking non-metallic inorganic minerals at high temperatures.
Ceramics
What is Transformaiton toughness?
Tetragonal —> monoclinic
Increase in size 3-4%
Tensile —> compressive
Transformation toughening
The ability of zirconia to arrest _______ ______ by changing its phase at the cracks edges from tetrgaonal to _______. Thus, the size of the molecules ______, and tesile stresses are replaced by _______ stresses.
crack propagation
monoclinic, increases
compresive
Why zirconia? (2)
The widespread use of CAD/CAM technology
Less expensive and less time consuming option when compared to porcelain fused to metal restorations
What are the 2 ways to classify zirconia?
Monlitihic vs layered
Single vs multi layered
The amount of yttria
Monolithic
The key factor in classifying dental zirconia is what?
yttria content
What form is 3 mol% yttrium oxie in?
tetragonal
What form is 5 mol% yttrium oxide in?
cubic
What form is 4 mol% yttrium oxide in?
tetragonal or cubic
Monolithic Zirconia 3y:
_____mol% ytrria
Greater than ____% tetragonal
Less than _____% cubic
High ___________
Low ___________
3
85%
15%
strength
translucency
What are the 2 uses of monolithic zirconia 3y?
Posterior singlu unit crowns
Fixed prosthetic devices such as birdges
Monolithic Zirconia 3Y: preperation
Margin?
Occlusal manufacutre?
Occlusal studies?
0.5-0.8mm margin, rounded shoulder or heavy chamfer
0.6mm
0.7-1.0mm
Monolithic Zirconia 4Y:
_____% tetragonal
______% cubic
_______ strength compared to 3Y
Acceptable _________
75%
25%
Lower
translucency
What is monolithic zirconia 4Y used for?
Single unit restorations (premolar area)
Monolithic Zirconia 4y: preparation
Margin?
Oclussal manfuacture?
Occlusal studies?
0.8-1mm rounded shoulder or heavy chamfer
1mm
1.2mm
Monolithic Zirconia 5y:
______% tetraonal
_______% cubic
Enhanced _________
Low _________
________ toughness
Less than 50%
More than 50%
translucency
strength
transformation
What are the 2 uses of monolithic zirconia 5y?
Anterior crowns
Alternative lithium disilicate (emax)
Monlithic Zirconia 5y prep:
Margin?
Occlusal manufacture?
Occlusal studies?
1mm, rounded shoulder or heavy chamfer
1mm
1.5mm
Layers Zirconia:
What does PFZ mean?
Core material?
Core?
High _________
Low __________
Porcelain fused to zirconia
Porcelain covered
3 mol% yttria
strength
translucency
Layered Zirconia:
Porcelain —> _________ zone
Reduction _____ and _______
Core mm?
Porcelain mm?
estheic
core and porcelain
0.6mm
1.2mm but less than 2mm
What happens when you have more than 2mm of unsupported porcelain on layered zirconia?
Porcelain chipping
Multi shade layered zirconia:
The yttria content is the _______ thoughout the whole restoration
The whole restoration is made of what?
The restoation has different ______ in it.
same
3Y,4Y, and 5Y
shades
% of part of multi layered zirconia block:
Dentin?
Transition layer 1?
Transistion layer 2?
Enamel layer?
35%
15%
15%
35%
Multi shade layered zirconia:
Preperation guidlines and indication follow what?
yttria content
Multi yttria layered zirconia:
The yttria content is ________ thought the restoration
The restoration is made of the same ______
The restoation has different _______ in it
different
shade
translucencies
Multi-yttria-layered:
_____ or _____ at the cervical
_____ at the incisal
Variable _________ and ________
3y or 4y
5y
strength and translucency
Multi yttria layered:
Dentin zone?
Incisal zone?
Very strong conditioned zirconium oxide in the dentin zone 1200 mpa
Highly translucent conditioned zirconium oxide in the incisal zone 650 mpa
When positioning a full contour crown, the ______ positioning in the disc determines the amount of _____ area in the restoration.
height
incisal
Multi-yttria-layered:
In theory the stronger phase of zirconia at the cervical part of the restoration does what?
Whats the reality?
increaes its fracture resistance
the weaker zirconia phase at the occlusal part of the restoation decreases its fracture resistance
Multi yttria layered:
Very ______ is known about preps and indications
Treat as what?
little
monlithic 5Y
Zirconia generations:
_________ classification
Based on ________ order
outdated
chronlogical
Generations: whats the material?
First?
Second?
Third?
Fourth?
Fifth?
3Y layered PFZ
3Y monolithic
5Y
4Y
Multi Y
Cementaiton:
Like _____ crown
However, use ________ after trying in zirconia, immediately before cementation
Because zirconia has a high affinity to ______ ______ so cleaning it with sodium hydroxide after the try in is neccessary.
PFM
Sodium hydroxide
salivary proteins
Can you bond Zirconia?
yes, but it has a different protocol compared to other ceramics and depends on the yttria content
What are the 3 steps of bonding zirconia?
Air particle abraion 50 micron aluminum oxide, under 2.5 bar pressure for 15 seconds
Adhesive phosphate monomer
Resin cement (dual or self cure)
Evidence based on 3Y zirconia:
Studies showed a decrease in the mechanical properties of ______ contatining zirconia after air particle abrasion.
cubic
When in doubt about a zirconia look at what? and not what?
mol% of yttria and not % by weight