orgo reagents reactants and products

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21 Terms

1
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Mark addition of H and Br reagent

HBr

2
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Antimark addition of H and Br reagent

HBr, H2O2

3
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Mark addition of H and OH (cation) reagent

H2SO4, HOR

4
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Antimark addition of H and OH reagent

1) H3B-THF

2) NaOH, H2O2

5
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Mark addition of H and OH (no cation) reagent

1) Hg(Oac)2, H20

2) NaBH4

6
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Adding Br and OH reagent

Br2, H2O

7
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Adding 2 H’s reagent

H2, Pt/Pd

8
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adding 2 OH’s ANTI reagent

1) paroxyacid (can end at epoxide product)

2) H2SO4, H2O

9
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adding 2 OH’s SYN reagent

1) OsO4

2) NaHSO3, H2O

10
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ozonolysis reagant

O3, Fe

11
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how to make alkene

add base

12
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how to make alkyne

add 2 eq. strong base (N- or H-) for double elimination

13
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how to zipper an alkyne to the end of a carbon chain

1) excess NH2 -

2) H2O

14
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concerted mechanism for alkynes leads to

syn-addition

15
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termolecular mechanisms for alkynes leads to

anti-addition

16
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/// hydrogenation to / reagent

H2, Pd/Pt

17
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/// hydrogenation to cis alkene reagent

H2, Lindlar’s catalyst

18
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/// hydrogenation to trans alkene reagent

Na(o), NH3

19
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/// mark hydration reagent

H2SO4, HgSO4, H2O

20
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/// antimark hydration reagent

1) HBR2

2) NaOH, H2O2

21
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/// ozonolysis

O3, H2O