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Mark addition of H and Br reagent
HBr
Antimark addition of H and Br reagent
HBr, H2O2
Mark addition of H and OH (cation) reagent
H2SO4, HOR
Antimark addition of H and OH reagent
1) H3B-THF
2) NaOH, H2O2
Mark addition of H and OH (no cation) reagent
1) Hg(Oac)2, H20
2) NaBH4
Adding Br and OH reagent
Br2, H2O
Adding 2 H’s reagent
H2, Pt/Pd
adding 2 OH’s ANTI reagent
1) paroxyacid (can end at epoxide product)
2) H2SO4, H2O
adding 2 OH’s SYN reagent
1) OsO4
2) NaHSO3, H2O
ozonolysis reagant
O3, Fe
how to make alkene
add base
how to make alkyne
add 2 eq. strong base (N- or H-) for double elimination
how to zipper an alkyne to the end of a carbon chain
1) excess NH2 -
2) H2O
concerted mechanism for alkynes leads to
syn-addition
termolecular mechanisms for alkynes leads to
anti-addition
/// hydrogenation to / reagent
H2, Pd/Pt
/// hydrogenation to cis alkene reagent
H2, Lindlar’s catalyst
/// hydrogenation to trans alkene reagent
Na(o), NH3
/// mark hydration reagent
H2SO4, HgSO4, H2O
/// antimark hydration reagent
1) HBR2
2) NaOH, H2O2
/// ozonolysis
O3, H2O