Alkene Reactions
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11 Terms
1
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HX
Hydrohalogenation (Markovnikov)
2
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HBr, ROOR
Anti-Markovnikov hydrohalogenation (radical mechanism)
3
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H₃O⁺
Acid-catalyzed hydration (Markovnikov)
4
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1) Hg(OAc)₂, H₂O 2) NaBH₄
Oxymercuration-demercuration (Markovnikov, no rearrangement)
5
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1) BH₃, THF 2) H₂O₂, NaOH
Hydroboration-oxidation (anti-Markovnikov, syn addition)
6
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Br₂
Bromination (anti)
7
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Br₂ / H₂O
Halohydrin formation (OH goes to more substituted carbon)
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H₂, Pt
Hydrogenation (syn addition)
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1) OsO₄ 2) NaHSO₃, H₂O
Syn dihydroxylation
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KMnO₄ (cold)
Syn dihydroxylation
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1) O₃ 2) DMS
Ozonolysis (cleavage to carbonyl compounds)
Note 
Flashcards (25)