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Electronegativity
the attraction an element has for the shared pair of electrons in the bond
Polar Covalent Bond
when there is an electronegativity difference between bonded atoms
-occurs when a pair of electrons is unequally shared between two atoms
Trends for Electronegativity
-increasing left to right
-decreasing top to bottom
Nonpolar Covalent Bond
a type of chemical bond where two atoms share a pair of electrons with each other
-occurs when there are no extra electrons in the central atom
VSPER
electron pairs orient around the central atoms in a way to minimize repulsion
-stands for valence shell electron pair repulsion
-used for predicting the molecular structures of molecules formed from nonmetals
Resonance
more than one Lewis Structure can represent a molecule
Unbonded pairs take up...
unbonded pairs take up more space than bonded pairs and push bonds closer
Ionic Bond
when one atom gives up one or more electrons to another atom
-the attraction between oppositely charged ions
Why are there no values for the noble gases?
it has a full orbital consisting of 8 electrons
Covalent Bond
atoms share electrons
What type of bond would you expect to form between two atoms of somewhat high electronegativity?
Covalent: share electrons because both have high valence electrons
In an ionic bond, the atom with the highest electronegativity will always form a positive or negative ion?
negative ion
True of false: in an ionic bond, the difference in electronegativities between the two bonding atoms is greater than the difference in a covalent bond
true
Ionic or covalent?-MgCl2
Ionic
Ionic or covalent?-Na2S
Ionic
Ionic or covalent?-H20
Covalent
Ionic or covalent?-H2S
Covalent
2 nonmetals creates what type of bond?
covalent bond
1 metal & 1 nonmetal creates what type of bond?
ionic bond
Partially negative atom
high electronegativity
Partially positive atom
low electronegativity
Why do molecules such as H2, Cl2, N2, and so on, have nonpolar bonds?
have identical electronegativities and the same size bond
Ionic, polar covalent, or nonpolar covalent?-CP
nonpolar covalent
Ionic, polar covalent, or nonpolar covalent?-SO
polar covalent
Ionic, polar covalent, or nonpolar covalent?-FeO
ionic
Ionic, polar covalent, or nonpolar covalent?-NH
polar covalent
What are the three most electronegative atoms on the periodic table?
Nitrogen, oxygen, fluorine (NOF)
Symmetrical (Polar or nonpolar?)
no side of the molecules has more negative or positive charge than another side; nonpolar
Octet Rule
the elements are typically surrounded by 8 electrons
Bond Pair
pair of electrons shared between 2 atoms forming covalent or polar-covalent bond
Lone Pair
electron pairs in a Lewis Structure that are not involved in bonding
Crystal Lattice
3D structure formed by repeating positive and negative ions
What is a formula unit?
smallest unit of crystal lattice
Properties of ionic compounds
hard, high melting point
Why are covalently bonded substances considered molecules when ionic substances are not?
molecules exist as a single particle
Properties of molecular substances
not as strong as ionic and has a low melting point
Exception: B
can only take 6 electrons
Exception: Be
can only take 4 electrons
Chemical Bond
a force that holds groups of two or more atoms together and makes them function as a unit