Adv Seps Key Equations

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Last updated 4:42 PM on 1/13/26
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7 Terms

1
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What is the equation for resolution of two peaks?

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Where tR is the retention time and W is the width of the peak at its base.

RS > 1.5 for fully resolved peaks.

<img src="https://knowt-user-attachments.s3.amazonaws.com/c42826b0-5e1e-448c-a193-38bf78e31a94.png" data-width="100%" data-align="center" alt="knowt flashcard image"><p>Where t<sub>R</sub> is the retention time and W is the width of the peak at its base.</p><p>R<sub>S</sub> &gt; 1.5 for fully resolved peaks.</p>
2
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What is the capacity factor (k’) equation?

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3
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What is the relationship between H, L and σ?

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σ is the standard deviation in length units

4
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What is the relationship between N, tR and τ?

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Where τ is the standard deviation in time units and N is the efficiency.

5
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What is the relationship between N, L and σ?

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Where N is the efficiency and σ is the standard deviation in length units.

6
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What is the equation for resolution of a peak in terms of efficiency?

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7
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What is the van Deemter equation and what are the components?

H = A + B/u + Cu

A: multiple flow paths

B: longitudinal diffusion

C: Mass transfer/equilibration time