Unit 4: Thermodynamics, Kinetics, and Enzymes

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What do enthalpy and entropy have to do with phase changes?

As you move from a solid to gas, you absorb more heat w

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Spontaneous Reaction vs. Non Spontaneous Reaction

Spontaneous reactions don’t need extra energy

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pairing an endergonic rxn with an exergonic one whose delta g “beats” (it’s so negative that when it’s added to a postive delta g the end result is still negative).

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Why is ATP used as a source of energy?

The full name of ATP is adenine triphosphate- because of the three phosphates (all of which have negative charges,) the molecule is incredibly unstable, and thus generates a lot of energy when it stablizes into ADP + Pi

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What are the two laws of Thermodynamics?

  1. energy cannot be created or destroyed

  2. When spontaneous rxns occur, the overall entropy of the universe increases.

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Activation Energy

the energy needed for spontaneous rxns to get started. Exergonic reactions are spontaneous so they will occur, but because of activation energy they occur really slowly- too slowly for the body and most life processes

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M

the energy needed for spontaneous rxns to get started. Exergonic reactions are spontaneous so they will occur, but because of activation energy they occur really slowly- too slowly for the body and most life processes

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