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when using ___ & ___ ; is is impossible to stop at the ______
-we have __________ of the alkyne
-H2 & Pd/C → alkene intermediate
-complete reduction
Lindlar’s Catalyst:
Pd/ CaCO3/ Pb(OAc)2/ quinoline : less reactive
Reduce alkyne to trans alkene:
-It is a ___________
-Steric hindrance at the _________ leads to the trans-selectivity of the dissolving metal reduction
-dissolving metal reduction
-vinyl carbanion

Reduce alkyne to trans alkene: Mechanism:












