Hydrogenation of Alkynes

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10 Terms

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when using ___ & ___ ; is is impossible to stop at the ______

-we have __________ of the alkyne

-H2 & Pd/C → alkene intermediate

-complete reduction

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Lindlar’s Catalyst:

Pd/ CaCO3/ Pb(OAc)2/ quinoline : less reactive

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Reduce alkyne to trans alkene:

-It is a ___________

-Steric hindrance at the _________ leads to the trans-selectivity of the dissolving metal reduction

-dissolving metal reduction

-vinyl carbanion

<p>-dissolving metal reduction</p><p>-vinyl carbanion</p>
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Reduce alkyne to trans alkene: Mechanism:

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