Acid-Base Chemistry: Terms and Definitions

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A set of 35 flashcards covering key terms and definitions related to acid-base chemistry to aid in exam preparation.

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39 Terms

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Ka

Equilibrium constant for the dissociation of HA to A- and H +.

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pKa

Negative log of the acid dissociation constant.

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Weak Acid

An acid that partially dissociates in solution.

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Weak Base

A base that partially accepts protons in solution.

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Dissociation

The process by which an acid or base breaks apart into ions in solution.

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Ion Constant of Water (Kw)

The equilibrium constant for the self-ionization of water.

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Conjugate Base

The species that remains after an acid donates a proton.

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Protonation

The process of adding a proton to a molecule.

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Resonance

The delocalization of electrons in a molecule.

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Equilibrium Constant (K)

A number that describes the ratio of concentrations of products to reactants at equilibrium.

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Acid Dissociation Constant (Ka)

Quantifies the strength of an acid in solution.

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pH

A measure of the acidity or basicity of a solution.

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Stronger Acid

An acid that has a larger Ka value and dissociates more completely.

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pK

Common shorthand for the negative logarithm of a concentration term, usually acidity.

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Barbiturates

A class of drugs that can act as weak acids in solution.

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Neutral Charge

A state in which a molecule has no overall charge (equal numbers of protons and electrons).

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Delocalized Charge

Charge that is spread over several atoms rather than localized on one atom.

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Sodium Salts of Acids

Salts that can increase the water solubility of weak acids.

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Concentration of H+

A measure of the amount of hydrogen ions present in a solution.

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True or False: A strong acid has a larger Ka than a weak acid.

True.

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True or False: The pKa of an acid is equal to its pKb of the conjugate base.

False.

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Equilibrium Reaction

The balance between the forward and reverse reaction in a chemical process.

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Proton Donor

An acid that donates protons (H+) in a reaction.

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Proton Acceptor

A base that accepts protons (H+) in a reaction.

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Ka of Weak Acid

Represented as a smaller value as compared to strong acids.

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Increased Water Solubility

Typically achieved by forming salts of weak acids.

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Strong Base

A base that completely dissociates in solution.

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Equivalence Point

The point in a titration where the amount of acid equals the amount of base.

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Buffer Solutions

Solutions that resist changes in pH when small amounts of acid or base are added.

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Concentration

The abundance of a constituent divided by the total volume of a mixture.

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Chemical Reaction

A process that leads to the transformation of one set of chemical substances to another.

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Weak Acid Example

Acetic acid (CH3COOH) is an example of a weak acid.

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Weak Base Example

Ammonia (NH3) is an example of a weak base.

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Acid-Base Chemistry

The study of reactions involving acids and bases.

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pH Scale

A logarithmic scale used to specify the acidity or basicity of an aqueous solution.

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H+ Ions

Hydrogen ions that determine the acidity of a solution.

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Ka and pKa Relationship

pKa = -log(Ka), showing their inverse relationship.

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Hydrogen Ion Concentration

Critical parameter that affects the pH level of a solution.

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Acid-Base Equilibria

The balance between acids and bases in a chemical system.