organic synthesis

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primary alcohol → aldehyde

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33 Terms

1

primary alcohol → aldehyde

acidified potassium dichromate

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2

secondary alcohol → ketone

acidified potassium dichromate

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3

carbonyl → alcohol

reduction - NaBH4

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4

alkene → alkane

hydrogenation - nickel catalyst

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5

NO2 → NH2

tin / HCl

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6

alkene → polyalkene

high pressure
catalyst

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7

alkene → dihalogenoalkane

Br2/Cl2
Eadd

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8

alkene → halogenoalkane

HBr/HCl
room temp
Eadd

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9

alkene → alcohol

conc H2SO4
Eadd
warm H2O
hydrolysis

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10

dihalogenoalkane → diol

aqueous KOH
heat under reflux
Nusub

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11

alkane → halogenoalkane

Br2/Cl2

UV

FRsub

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12

halogenoalkane → alkene

alcoholic KOH

heat under reflux

elimination

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13

halogenoalkane → alcohol

aqueous KOH

heat under reflux

Nusub

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14

halogenoalkane → nitrile

KCN in ethanol

heat under reflux

NuSub

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15

halogenoalkane → primary amine

alcoholic NH3 in excess

heat under pressure

NuSub

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16

halogenoalkane → secondary amine , tertiary amine, quaternary salt

limited NH3

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17

alcohol → alkene

conc. H2SO4

elimination

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18

alcohol → ester

carboxylic acid

H2SO4

heat

esterification

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19

aldehyde → alcohol

NaBH4

NuAdd

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20

aldehyde → carboxylic acid

excess acidified potassium dichromate

heat under reflux

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21

aldehyde → hydroxynitrile

KCN

H2SO4

NuAdd

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22

ketone → alcohol

NaBH4

NuAdd

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23

ketone → hydroxynitrile

KCN

H2SO4

NuAdd

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24

carboxylic acid → ester

alcohol

H2SO4

heat

esterification

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25

nitrile → carboxylic acid

HCl

hydrolysis

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26

nitrile → primary amine

LiAlH4 in ether

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27

acyl chloride / acid anhydride → carboxylic acid

H2O

NuAddEl

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28

acyl chloride / acid anhydride → ester

alcohol

NuAddEl

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29

acyl chloride / acid anhydride → secondary amide

primary amine

NuAddEl

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30

acyl chloride / acid anhydride → primary amide

NH3

NuAddEl

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31

primary amine →

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32

primary amine →

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33
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