factors affecting reaction rates terms

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41 Terms

1
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part 1: effect of metal activity

purpose?

to see how the type of metal affects reaction rate when reacting with the same acid.

2
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what stayed consistent for part 1?

HCl, same concentrations

temperature and volume of acid

setup and timing method

3
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what changed for part 1?

type of metal

  • mg

  • zn

  • cu

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Magnesium Reaction Performed - Part 1

Mg(s) + 2 HCl(aq) → MgCl₂(aq) + H₂(g)

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Zinc Reaction Performed - Part 1

Zn(s) + 2 HCl(aq) → ZnCl₂(aq) + H₂(g)

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Copper Reaction Performed - Part 1

Cu(s) + 2 HCl(aq) → No Reaction

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Mg Reaction Observed - Pt 1

rapid bubbling, vigorous reaction

fastest 

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Zn Reaction Observation - Pt 1

moderate bubbling

moderate

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Cu Reaction Observed - Pt 1

no bubbling, no visible change

no reaction

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conclusion of part 1

reactivity determines rate

mg > zn > cu because magnesium is more active than hydrogen, zinc is less reactive, and copper is below hydrogen in the activity series 

it cannot replace H+

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part 2 - effect of acid strength

purpose 

to determine how the strength of the acid affects the rate of hydrogen gas formation with a constant metal

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what stayed consistent in part 2?

metal: magnesium (same size and amount)

set up, timing method, and overall temperature conditions (as much as possible).

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what changed in part 2?

type of acid:

  • H₂SO₄

  • HCl

  • H₃PO₄

  • CH₃COOH

each acid has a different ability yo ionize and release H+ ions

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H₂SO₄ Reaction Performed - Pt 2

Mg + H₂SO₄ → MgSO₄ + H₂

Fastest Rate

Strong Acid Strength

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HCl Reaction Performed - Pt 2

Mg + 2 HCl → MgCl₂ + H₂

Moderate Rate

Strong Acid Strength

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H₃PO₄ Reaction Performed - Pt 2

3 Mg + 2 H₃PO₄ → Mg₃(PO₄)₂ + 3 H₂

Slow Rate

Weak Acid Strength

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CH₃COOH Reaction Performed

Mg + 2 CH₃COOH → Mg(CH₃COO)₂ + H₂

Weak Rate

Weakest Acid Strength

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conclusion of part 2

all acids reacted with magnesium only

reaction rate increased with acid strength - strong acids (H₂SO₄, HCl) ionize completely, realsing more H+ ions - more collisions with Mg - faster H2 gas formation. 

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part 3 - effect of concentration

purpose?

to see how changing the concentration of reactants (HIO₃) affects reaction rate.

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what stayed consistent for part 3?

  • same temperature, same reactants (HIO₃, H₂SO₃, starch).

  • total solution volume kept constant (2.0 mL).

  • same color indicator method (appearance of blue color)

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what changed for part 3?

concentration of HIO3 solution

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reactions performed during part 3

HIO₃(aq) + H₂SO₃(aq) → I₂(aq) + H₂SO₄(aq) + H₂O(l)
I₂ + starch → blue complex (signals reaction completion).

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sample calculation for part 3

[HIO₃] = (0.010M) (VHIO₃​) / Vtotal​

for 11 drops (0.55 mL = 5.5 × 10⁻⁴ L):

Vtotal​ ≈ 1.25 × 10−3L ⇒ [HIO₃] = 0.0046M

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conclusion for part 3

as concentration goes up, the rate also goes up.

more reactant particles per volume - higher collision frequency - faster color change (blue complex forms sooner).

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part 4: effect of temperature

purpose?

to determine how temperature changes reaction rate for the same reactants

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what stayed consistent for part 4

same chemicals and concentrations

same procedure and timing method

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what changed for part 4

temperature of the solution

(cold, room temp, warm)

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reaction used for part 4

same iodine clock reaction as part III:
HIO₃ + H₂SO₃ → I₂ + H₂SO₄ + H₂O
(I₂ + starch → blue color).

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ice bath observations - pt 4 - 3 degrees celsius 

very slow color change

slow rate 

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room temp observations - pt 4 - 31 degrees celsius

moderate time

medium rate 

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warm observations - pt 4 - 68 degrees celsius

very quick blue color

fastest rate 

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conclusion of part 4

higher temperature means higher average kinetic energy which leads to more frequent and energetic collisions.

more molecules exceed activation energy means faster rate 

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part 5: effect of catalyst

purpose?

to test how adding a catalyst affects the rate of decomposition of hydrogen peroxide.

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what stayed consistent in part 5?

amount and concentration of H₂O₂ solution.

same setup and timing method

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what changed in part 5?

presence or absence of catalyst (MnO₂).

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reaction performed in part 5

2 H₂O₂(aq) → 2 H₂O(l) + O₂(g)

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catalyst in part 5

MnO₂ (manganese dioxide)

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observations with MnO₂

immediate and rapid bubbling of O₂ gas.

solution turns black (MnO₂ solid particles).

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observations without MnO₂

very slow gas release.

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conclusion of part 5

catalyst lowers the activation energy (Ea) allowing the reaction to proceed faster.

MnO₂ is not consumed; it only provides an alternate reaction pathway.

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