rp11 eqns - identification of TM compounds

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17 Terms

1
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give the ionic eqn for the reaction between the Al3+ complex and dilute NaOH in moderation:


Al(H2O)3(OH)3 + OH- → [Al(OH)4]- + 3H2O

2
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give the ionic eqn for the reaction between the Al3+ complex and dilute NaOH in XS:

Al(OH)3(H2O)3 + OH- → [Al(OH)4(H2O)2]- + H2O

3
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give the ionic eqn for the reaction between the Al3+ complex and NH3:

[Al(H2O)6]3+ + 3NH3 → [Al(OH)3(H2O)3] + 3NH4+

4
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give the ionic eqn for the reaction between the Al3+ complex and Na2CO3:

2[Al(H2O)6]3+ + 3CO32- → 2[Al(OH)3(H2O)3] + 3CO2 + 3H2O

5
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give the ionic eqn for the reaction between the Al3+ complex and HCl:

Al(H2O)3(OH)3 + 3HCl → [Al(H2O)6]3+ + 3Cl-

6
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give the ionic eqn for the reaction between the Fe3+ complex and dilute NaOH:

[Fe(H2O)6]3+ + 3OH-  → Fe(H2O)3(OH)3 + 3H2O​

7
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give the ionic eqn for the reaction between the Fe3+ complex and NH3:

[Fe(H2O)6]3+ + 3NH3Fe(H2O)3(OH)3 + 3NH4+​

8
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give the ionic eqn for the reaction between the Fe3+ complex and Na2CO3:

2[Fe(H2O)6]3+ + 3CO32-Fe(H2O)3(OH)3 + 3CO2 + 3H2O​

9
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give the ionic eqn for the reaction between the Fe3+ complex and HCl: 

[Fe(H2O)6]3+ + 4Cl- → [FeCl4]- + 6H2O

10
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give the ionic eqn for the reaction between the Fe2+ complex and dilute NaOH:

[Fe(H2O)6]2+ + 2OH-Fe(H2O)4(OH)2 + 2H2O

11
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give the ionic eqn for the reaction between the Fe2+ complex and NH3:

[Fe(H2O)6]2+ + 2NH3[Fe(H2O)4(OH)2] + 2NH4+

12
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give the ionic eqn for the reaction between the Fe2+ complex and Na2CO3:

[Fe(H2O)62+ + CO32-FeCO3 + 6H2O

13
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give the ionic eqn for the reaction between the Cu2+ complex and dilute NaOH:

[Cu(H2O)6]2+ + 2OH- [Cu(H2O)4(OH)2] + 2H2O

14
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give the ionic eqn for the reaction between the Cu2+ complex and NH3 in moderation:

[Cu(H2O)6]2+ + 2OH- [Cu(H2O)4(OH)2] + 2H2O

15
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give the ionic eqn for the reaction between the Cu2+ complex and NH3 in XS:


[Cu(H2O)4(OH)2] + 4NH3[Cu(NH3)4(H2O)2]2+ + 2H2O + 2OH-

16
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give the ionic eqn for the reaction between the Cu2+ complex and Na2CO3:

[Cu(H2O)6]2+ + CO32-CuCO3 + 6H2O

17
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give the ionic eqn for the reaction between the Cu2+ complex and HCl:

[Cu(H2O)6]2+ + 4Cl- CuCl42- + 6H2O