• no change in volume therefore W = 0;
• When heat is transferred from reactor to gas, internal energy of gas increases;
• When heat is transferred from gas to surroundings, internal energy of gas decreases;
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• entropy of the gas increases as energy is transferred from the reactor;
• entropy of the surroundings increases as energy is transferred from the gas;
• entropy of gas decreases on cooling;
• overall the entropy of the total system increases;