1/21
Vocabulary flashcards covering key thermodynamics concepts: temperature scales and conversions, thermal expansion, phase changes, calorimetry, and related properties.
Name | Mastery | Learn | Test | Matching | Spaced |
---|
No study sessions yet.
Relation between Celsius, Kelvin, and Fahrenheit scales
TC = TK − 273.15; TF = (9/5)·TC + 32; TC = (TF − 32)·5/9; TK = TC + 273.15.
Celsius and Fahrenheit equal reading
They read the same value at −40.0°.
Kelvin and Fahrenheit equal readings
They are numerically equal at 574.59° (K = °F numerically).
Kelvin and Celsius equal readings
Never (they never have the same numerical value at any temperature).
Healthy human body temperature
Approximately 37°C or 98.4°F.
Fusion
The process of transforming a solid into a liquid.
Melting point
Temperature at normal pressure (1 atm) at which a solid turns into liquid; ice melts at 0°C.
Vaporization
Transformation of a liquid to a gaseous state. Can occur by evaporation or boiling.
Evaporation
Liquid slowly changes to vapor from its exposed surface at any temperature.
Factors affecting evaporation
Flow of air, exposed surface area, nature of the liquid, air pressure, temperature, and dryness of air.
Boiling
Liquid rapidly converts to vapor upon heating, via application of heat.
Boiling point
Temperature at which vapor pressure equals atmospheric pressure; depends on external pressure.
Condensation (liquefaction)
Process of transforming a gaseous substance into a liquid.
Solidification
Process of transforming a liquid substance into a solid.
Latent heat of fusion (L_f)
Heat required to change 1 kg of a solid at its melting point to liquid, at the same temperature. Q = Lf m. Ice Lf ≈ 334000 J·kg⁻¹.
Latent heat of vaporization (L_v)
Heat required to change 1 kg of a liquid to gas at its boiling point, at constant temperature. Q = Lv m. Water Lv ≈ 334000 J·kg⁻¹.
Heat capacity (C)
Amount of heat required to raise the temperature of a body by 1 K. C = Q/(T₂ − T₁). Units: J·K⁻¹.
Specific heat (c or S)
Amount of heat required to raise the temperature of 1 kg of a substance by 1 K. S = Q/(m ΔT); units: J·kg⁻¹·K⁻¹.
Relation: heat capacity and specific heat
C = m × S; equivalently S = C/m; Therefore C = mS and S = C/m.
Calorimeter
A device used to measure the amount of heat involved in a chemical or physical process.
Principle of calorimetry
When two bodies at different temperatures are in contact, heat flows until thermal equilibrium; heat lost by the hotter body equals heat gained by the cooler body.
Regelation
Melting of a solid into liquid under pressure and re-solidification on release of pressure.