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Quantum Mechanics
Quantum Mechanics
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1
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What does the wavefunction (Ψ) describe?
The movement of a particle.
2
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What is probability density (Ψ²)?
The probability of finding the particle in a region.
3
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Where is a node located?
Where the probability of finding an electron is zero.
4
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How many nodes do wavefunctions have?
Wavefunctions have (n-1) nodes.
5
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What can an electron do at a node?
An electron can never be at a node, but can 'cross' nodes as they are delocalized standing waves.
6
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For which energy levels do s orbitals exist?
For all energy levels n ≥ 1.
7
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What is the angular momentum quantum number (l) for s orbitals?
L = 0.
8
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For which quantum number do p orbitals exist?
Exists for n ≥ 2.
9
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What is the angular momentum quantum number (l) for p orbitals?
L = 1.
10
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For which quantum number do d orbitals exist?
Exists for n ≥ 3.
11
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What do penetrating orbitals refer to?
Orbitals with radial probability closer to the nucleus.
12
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What is the difference between paramagnetism and diamagnetism?
Paramagnetism has unpaired electrons and is drawn towards magnets; diamagnetism has paired electrons and is slightly repelled by magnets.
13
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What does the principle quantum number (n) define?
The size and energy of the orbital.
14
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What is the allowed value for the principle quantum number (n)?
Must be positive whole numbers.
15
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How do you calculate the number of orbitals in a shell?
Using the formula n².
16
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What does the angular momentum quantum number (l) define?
The 3D shape of the orbital.
17
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What are the possible values for the angular momentum quantum number (l)?
Any integer from 0 to (n-1).
18
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What does the magnetic quantum number (ml) define?
The spatial orientation of the orbital.
19
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What are the allowed values for the magnetic quantum number (ml)?
From -l, …, 0,... +l.
20
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How many spatial orientations are there of orbitals in a subshell?
2l + 1.
21
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How many electrons can an s sublevel hold?
2 electrons.
22
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How many electrons can a p sublevel hold?
6 electrons.
23
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How many electrons can a d sublevel hold?
10 electrons.
24
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How many electrons can an f sublevel hold?
14 electrons.
25
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What does the spin quantum number (ms) define?
The spin axis of an electron.
26
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What are the allowed values for the spin quantum number (ms)?
+½ or -½.
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How many electrons are allowed per orbital?
Only two electrons are allowed per orbital.