Synthetic Transformations
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20 Terms
What is the reagent?
Hg(OAc)2, H20 [THF solvent] + NaBH4
![<p>Hg(OAc)2, H20 [THF solvent] + NaBH4</p>](https://knowt-user-attachments.s3.amazonaws.com/1599287e-e825-4558-9f2c-0cdd8362eef6.png)
What is the product?
R2HC-CHOH-CH3
What is the reactant?
R2HC-CH--CH2
Reaction type and mechanism
Markovnikov addition of H and OH with No carbocation rearrangement
What are the reagents? R2HC-CH--CH2 to R2HC-CHOR-CH3
Hg(OAc)2, HOR + NaBH4
What is the product?
R2HC-CH--CH2 with Hg(OAc)2, HOR + NaBH4
R2HC-CHOR-CH3
What is the reactant?
Hg(OAc)2, HOR + NaBH4 resulting in R2HC-CHOR-CH3
R2HC-CH--CH2
What is the reaction and mechanism?
Markovnikov addition of H and OR with No carbocation rearrangement
What are the reagents? R2C--CHR to R2CH-CHROH
BH3 + H2O2, NaOH
What is the product? R2C--CHR with BH3 + H2O2, NaOH
R2CH-CHROH
What is the reactant?
BH3 + H2O2, NaOH resulting in R2CH-CHROH
R2C--CHR
Reaction and mechanism
Anti-Markovnikov Addition of H and OH
What are the Reagents? R2C--CHR to R2CH--CHRBr
HBr, Peroxides (ROOR) + heat/light
What is the product?
R2C--CHR with HBr, Peroxides (ROOR) + heat/light
R2CH--CHRBr
What is the reactant?
adding HBr, Peroxides (ROOR) + heat/light resulting R2CH--CHRBr
R2C--CHR
What is the reaction and mechanism?
Anti-Markovnikov Addition of H and Br
What are the reagents? R2C--CHR to R2XC-CH2R
HX + cold, dark, no peroxides
What is the product? R2C--CHR with HX + cold, dark, no peroxides
R2XC-CH2R
What is the reactant?
adding HX + cold, dark, no peroxides resulting R2XC-CH2R
R2C--CHR
Reaction and mechanism
Markovnikov Addition of H and X (X being Cl, Br, or I)
Note 
Flashcards (31)