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sources of freshwater
ground water (29.9%)
available at point of needs at little cost
surface water 0,34
usually requires extensive purification
ocean water (96.5%)
costly to desalinate
fresh water is an increasingly scarce resource due to…
population growth
change in water consumption pattern
climate change
total water withdrawals by water-use category in the u.s. from 1950-2015
rapid increase from 1950-1980
slow decline after 1980
water pollution sources - point vs non point sources
point sources: pollutants enter the waterways at well-defined locations (sewage treatment plants and industrial facilities’ waste pipe)
easier to control & monitor
non-point sources: those which run off or seep into waterways from broad areas of land (agriculture, constructive activities, acid mine drainage, settling of air pollutants, landfill leachate)
harder to control & monitor
major drinking water contaminants
pathogenic microbial
bacteria - cholera
viruses - hep A
protozoans - giardia lamblia & cryptosporidium
chemicals
ingorganic contaminants - arsenic fluriode, lead, nitrates
synthetic organic pollutants - pesticides and herbicides, industrical solvents
disinfection by-products - tryhalomethanes
safe drinking water act (SDWA) 1974, 1986, 1996
main federal law that ensures the quality of American's’ drinking water
EPA established max contaminant levels for ore than 80 pollutants
criterria must be met by water supplied by community water system
clean water act
main federal law that governs water pollution (ensure water is fishable & swimmable)
1972 amendments to Federal Water Pollution Control Act (1948) lead to the Clean Water Act
Aim to restore and maintain the chemical, physical, and biological integrity of waters by preventing point and nonpoint pollution sources
water purification goal
provide safe source of water that meets wuality objectives at a reasonable cost
drinking water treatments/water purification process (top to bottom)
raw water/drinking water source
coagulation (chemicals added to neutralize the charge of dirt and dissolved particles), then flocculation (water is gently stirred to bind those paticles together into larger clumps called "floc")
sedimentation (heavy floc particles sink)
filtration (remove remaining small solids)
disinfection (typically chlorine to kill pathogenic microorganisms)
distribution system
5 water disinfection requirements
Must destroy bacteria, viruses, and amebic cysts in water within a reasonable time despite all variations in water temperature, composition, and concentration of contaminants
Must not be toxic for humans and domestic animals
Must not be unreasonable in cost and safe and easy to store, handle
Residual concentration in the treated water must be easily automatically determinable
Must be sufficiently persistent so that the disappearance of the residual would be a warning of contamination
chlorine pros
favored disinfectant for water supplies because it is convenient, cheap, & residual
chlorine cons
doesn’t kill protozoan cysts (plant) & some resistant viruses
chlorine reaction by-products (unintended & harmful chemical compound)
may react w/ organic compounds to create disinfecton by-products (trihalomethanes)
surface water, high in dissolved natural organic material, are especially vulnerable to THM
THMS are potentially carcinogenic
ozone pros
highly effective against all types of microbes (bacteria, viruses, fungi, & protozoa (seed))
ozone cons
expensive, unstable (must be produced on-site b/c of short shelf life), high toxicity, create harmful by-products, highly complicated maintenance and operation, & no lasting residuals
uv radiation pros
very effective against bacteria, fungi, & protozoa (seed); no known formation of disinfection by-products
uv radiation cons
not so effective against viruses, no lasting residuals, & expensive
water fluoridation
one of the ten great public health achievements of 20th century
adjustment of fluoride concentration to 0.7 ppm to prevent tooth decay
why treat wastewater?
carries pathogens & toxic chemicals
low dissolved oxygen
adds nutrients (nitrate & phosphate) to cause excessive algae growth
increases solids or sediments in streams (turbidity increase aka murky water)
dissolved oxygen (DO)
how much oxygen is "dissolved" in water & available for aquatic organisms to breathe; essentially the "breathable air" for underwater life
if the bacteria use all the oxygen, the fish and other aquatic life suffocate because the DO levels become too low
oxygen sag curve
Dissolved Oxygen (DO): amount of oxygen available for aquatic life. It drops sharply (the "sag"), which is bad, as bacteria consumed all of it to break down waste & none for aquatic life
Biochemical Oxygen Demand (BOD): measures how much oxygen bacteria need to decompose the organic matter present. It is highest at the point of pollution and decreases as the waste is broken down.
why are nitrates & phosphates pollutants & the source?
Eutrophication
Premature aging of aquatic system
Excessive nutrient level and excessive growth of algae eventually fills up a lake
Source
Domestic sewage and animal sewage, fertilizer runoff, detergent
municipal sewage treatment
improve quality of wastewater so it can be discharged into a waterway w/o disrupting the aquatic envrionment or causing human health problems in the form of waterborne disease & not cause oxygen sag curve
water treatment process stages
primary: physical & mechanical removal of solids
secondary: biological process like bacteria to remove paticles that dissolved in the water
tertiary: only required if the remaining 5% of contaminate need to be removed
Filtration
Removal of nutrients, such as nitrogen and phosphorus
Removal of other specific contaminants
Disinfection to destroy bacteria which can cause disease in humans
chlorination of treated wastewater concerns
although chlorination before water discharge is standard, there are concerns because:
effective in killing bacteria but less so in relation to protozoans and viruses
chloramines are formed which may be toxic to aquatic life
expensive
technical issues related to pathogen detection
impossible to monitor for all pathogens
direct environmental pathogens detection from is technically demanding, often tedious, slow to produce results, sometimes unreliable, and expensive
low number of pathogens
human or non-human strains
pathogens difficult to detect cannot determine viability
need large sample volumes
fewer labs equipped or staffed day to weeks for results
Indicator organisms signal recent fecal contamination
signal recent fecal contamination
Universally present in large numbers in warm blooded animal fecal materials
Readily detectable by simple methods
Do not grow in natural waters
Persistence in water treatment regimes is similar to that for pathogens
Microbal Indicators of Fecal Contamination
Traditional approach to assess the sanitary quality of water with respect to fecal contamination
Quantify bacteria commonly present in intestines of warm blooded animals
High numbers
Easy to measure
Surrogates for pathogens, especially bacterial pathogens
May NOT be reliable indicators of viruses and parasites
Bacterial Indicators of Fecal Contamination in Water (think of picture)
Total coliforms: standards for drinking waters
Fecal (“thermotolerant”) coliforms: standards for wastewater effluents, biosolids, surface waters, shellfish harvest waters
Eschrichia coli (E. coli): the “fecal” coliform; standards for drinking water
diseases related to water
Water-borne diseases: cause by ingestion of water that are contaminated by
Pathogenic microorganisms (choleria & typhoid)
Chemicals that have adverse effect on health (arsenic & pesticides)
Water-washed disease: caused by poor personal hygiene and skin and eye contact with contaminated water (scabies, flea, lice, & tick-borne diseases)
Water-based disease: cause by parasites in intermediate organisms living in contaminated water (schistosomiasis)
Water-related diseases: caused by insect vectors, especially mosquitoes, that breed (malaria & dengue)
3 Water-borne Diseases
Cholera
Cryptosporidum
Arsenic-associated disease
Cholera Epidemic in Soho, London 1854
when the pump handle was removed, no new cases were diagnosed in Broad Street
Cholera in Haiti, 2010
This cholera epidemic appear to be the largest ever recorded in a single country during the past 50 years
Outbreak worsened by earthquake: thousands homeless and destroyed sanitation and water infrastructure
1993 Milwaukee Cryptosoridium Outbreak
their water and sewage system was connected
Clinical manifestations included watery, diarrhea, adobminal cramps, fever, vomiting
extreme Precipitation and Water-borne Disease Outbreaks
In Northern America, most documented waterborne disease outbreaks occur after extreme precipiation events
Rainfall: transport and dissemination fo infectious agents
Flooding: sewage treatment plants overflow; water sources contaminated, secondary shortage of clean drinking water
arsenic
element in the Earth’s crust
No smell, no taste
Most arsenic compounds dissolve in water
arsenic compounds are classified as:
inorganic arsenic (combined w/ oxygen, chlorine, or sulfur)
drinking water is a major exposure to inorganic arsenic
organic arsenic (combines w/ carbon & hydrogen)
organic arsenic is usually less harmful than inorganic arsenic
other exposure pathways to inorganic arsenic
Wood preservatives
Electronics industry
Manufacturing of copper and other metals
Medicine
where in the u.s. are arsenic concentrations high
western states
health effects of arsenic (can mimic phosphate actions)
Skin: Bowen’s disease
Cancer: skin, liver, lung, kidney, bladder, prostate
Non-cancer
Circulatory problems
Stocking & glove neuropathy (numbness)
Kidney damage
Keratosis, abnormal pigmentation, hair loss
nerve damage