The third Law of thermodynamics/entropy principle

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12 Terms

1
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what is the third law of thermodynamics?

the entropy of a pure crystalline substance at absolute zero temperature is zero

2
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what is absolute entropy?

entropy relative to the entropy of a pure crystalline substance at absolute zero (which is zero)

3
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what is the order of entropy of the three main states of matter?

Gas > Liquid > Solid

4
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what is the increase of entropy principle?

entropy is always increasing

5
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why is entropy generated during irreversible processes?

due to the presence of irreversibilties

6
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how can you identify the reversibility of a system based off of entropy generated?

Entropy generated < 0 IMPOSSIBLE

Entropy generated = 0 REVERSIBLE

Entropy generated > 0 IRREVERSIBLE

7
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what is the equation of entropy for an isothermal case?

δQ/T

8
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what is the basic energy direction convention?

Q in +

Q out -

W in -

W out +

9
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What is the sign convention for a carnot heat engine and for the environment?

knowt flashcard image
10
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when is entropy conserved?

entropy is only conserved during IDEALISED REVERSIBLE PROCESSES and increases during all actual processes

11
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how can you work out quality from steam tables using entropy?

S = S(f) + xS(fg)

12
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what is an isentropic process?

entropy change = 0