IEB CHEMISTRY DEFINITIONS

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52 Terms

1

Molar mass

The mass in grams of one mole of a substance

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2

Homogeneous mixture

A homogenous mixture of solute and solvent

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3

Solute

A substance that is dissolved in a solution.

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4

Solvent

A substance in which another substance is dissolved, forming a solution

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5

Concentration

The amount of solute per unit volume of solution

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6

Yield

A measure of the extent of a reaction, generally measured by comparing the amount of product against the amount of product that is possible

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7

Intramolecular bond

A bond that occurs between atoms within the molecules

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8

Covalent bond

A sharing of at least one pair of electrons by two non-metal atoms

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9

Non-Polar (Pure) Covalent Bond

An equal sharing of electrons

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10

Polar covalent

The unequal sharing of electrons leading to a dipole forming

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11

Ionic bond

Transfer of electrons and subsequent electrostatic attraction

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12

Electronegativity

Measure of the tendency of an atom to attract a bonding pair of electrons

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13

Metallic bond

Being between a positive kernel and a sea of delocalised electrons

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14

Intermolecular Force

A weak force of attraction between molecules, ions, or atoms of noble gases

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15

Heat of Reaction (ΔH)

The net change of chemical potential energy of the system.

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16

Exothermic reaction

Reactions which transform chemical potential energy into thermal energy

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17

Endothermic

Reactions which transform thermal energy into chemical potential energy

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18

Activation Energy

The minimum energy required to start a chemical reaction

OR

The energy required to form the activated complex

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19

Activated Complex

High energy, unstable, temporary transition state between the reactants and the products

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20

Reaction Rate

The change in concentration per unit time of either a reactant or product

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21

Catalyst

a substance that increases the rate of the reaction but remains unchanged at the end of the reaction

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22

Closed System

One in which mass is conserved inside the system but energy can enter or leave the system freely

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23

Open System

One in which both energy and matter can be exchanged between the system and its surroundings

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24

Le Chatelier's Principle

When an external stress (change in pressure, temperature or concentration) is applied to a system in a dynamic chemical equilibrium, the equilibrium point will change in such a way as to counteract the stress

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25

Acid

BL: A proton donor

A: A substance that releases H+ions in an aqueous solution

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26

Base

BL: A proton acceptor

A: A substance that releases OH− ions in an aqueous solution

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27

Ionisation

The reaction of a molecular substance with water to produce ions

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28

Strong acid

An acid the ionises completely in an aqueous solution

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29

Weak Acid

An acid that ionises only partially in an aqueous solution

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30

Dissociation

The splitting of an ionic compound into its ions

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31

Strong base

A base that dissociates completely in an aqueous solution

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32

Weak base

A base that dissociates on partially in an aqueous solution

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33

Amphoteric (or amphiprotic) substance

A substance that can act as either an acid or a base

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34

Kw

Define Kw for water at 25°C as Kw= [H3O+][OH-]

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35

A salt

A substance in which the hydrogen of an acid has been replaced by a cation

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36

Hydrolysis

A reaction of an ion with water

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37

Neutralisation/Equivalence point

The point where an acid and base have reacted so neither is in excess

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38

Standard Solution

A solution of known concentration

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39

Redox reaction

A reaction involving the transfer of electrons

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40

Oxidation

The loss of electrons

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41

Reduction

The gain of electrons

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42

Oxidising agent

A substance that accepts electrons

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43

Reducing agent

A substance that donates electrons

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44

Anode

The electrode where oxidation takes place

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45

Cathode

The electrode where reduction takes place

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46

Electrolyte

A substance that can conduct electricity by forming free ions when molten or dissolved in solution

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47

Hydrocarbon

A compound containing only carbon and hydrogen atoms

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48

Saturated Compound

A compound in which all of the bonds between carbon atoms are single bonds

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49

Unsaturated Compound

A compound in which there is at least one double and/or triple bond between carbon atoms

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50

Functional Group

An atoms or a group of atoms that form the centre of chemical activity in the molecule

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51

Homologous Series

A series of similar compounds which have the same functional group and have the same general formula, in which each member differs from the previous one by a single CH2 unit

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52

Structural isomer

Compounds having the same molecular formula but different structural formula

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