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15 Terms

1
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What happens when a primary alcohol is oxidised with acidified dichromate?

It forms an aldehyde (and further oxidation gives a carboxylic acid).

2
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What conditions are needed to oxidise a primary alcohol into an aldehyde?

Acidified potassium dichromate (K2Cr2O7/H+) under controlled heating and distillation.

3
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What conditions are needed to oxidise a primary alcohol into a carboxylic acid?

Acidified potassium dichromate (K2Cr2O7/H+) with reflux.

4
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What happens when a secondary alcohol is oxidised with acidified dichromate?

It forms a ketone.

5
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What happens when an aldehyde is oxidised with acidified dichromate?

It forms a carboxylic acid.

6
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What happens when an aldehyde reacts with a Grignard reagent followed by acidic work-up?

It forms a secondary alcohol.

7
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What happens when a carboxylic acid reacts with an alcohol in the presence of concentrated sulfuric acid?

An ester is formed (esterification).

8
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What conditions are needed to form an ester from a carboxylic acid and an alcohol?

Heat with concentrated sulfuric acid (catalyst).

9
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What happens when an alcohol is heated with concentrated sulfuric acid?

It dehydrates to form an alkene (elimination).

10
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What happens when two alcohol molecules react with concentrated sulfuric acid?

They condense to form an ether.

11
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What happens when an alkene reacts with water in the presence of concentrated sulfuric acid?

It forms an alcohol (hydration).

12
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What happens when an alkene reacts with hydrogen halide (HX)?

It forms an alkyl halide (electrophilic addition).

13
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What conditions are needed to form an alcohol from an alkyl halide?

Hydrolysis with aqueous base (NaOH(aq)) or acidic conditions (H2O with H+).

14
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What conditions are needed to form an alkyl halide from an alcohol?

Reaction with HX (hydrogen halide) under acidic conditions.

15
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