Energetics definitions

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12 Terms

1

Standard enthalpy change of reaction

The enthalpy change when the number of moles of reactants as stated in the equation react under standard conditions of 100kPa and 298K.

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2

Standard enthalpy change of formation

The enthalpy change when one mole of a compound is formed from its elements, in their most stable states, under standard conditions of 100kPa and 298K.

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3

Standard enthalpy change of combustion

The enthalpy change when 1 mol of a substance is completely burned in oxygen under standard conditions, all reactants and products being in their standard conditions of 100kPa and 298K.

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4

Standard enthalpy change of neutralisation

The enthalpy change, under standard conditions, when 1 mol of water is produces as a result of the reaction between an acid and an alkali.

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5

Enthalpy change of solution

The enthalpy change when 1 mol of a compound completely dissolves in water under standard conditions.

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6

Enthalpy change of hydration

The enthalpy change when 1 mol of gaseous ions is dissolved in water to form 1 mol of aqueous ions under standard conditions.

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7

Enthalpy change of atomisation

The enthalpy change when 1 mol of gaseous atoms is formed from its element in its standard state.

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8

Lattice enthalpy

The enthalpy change that takes place when 1 mol of an ionic solid is formed from its gaseous ions.

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9

First electron affinity

Energy change that takes place when 1 mol of atoms in the gaseous state gain 1 mol of electrons to form 1 mol of gaseous 1- ions.

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10

First ionisation energy

The energy change that takes place when one electron is lost from each of a mole of atoms in the gaseous state to form one mole of gaseous 1+ ions.

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11

Hess’ Law

If the initial and final conditions are the same, then the total enthalpy change will be the same, regardless of the route taken between reactants and products.

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12

Giant ionic lattice

Opposite charged ions are held together by strong electrostatic forces of attraction in a huge three-dimensional structure.

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