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What are the functions of fat in food?
Flavor, emulsify, satiety, flaky texture, transfer heat, leaven, prevent sticking
Butyric acid
4:0
Lauric acid
12:0
Palmitic acid
16:0
Palmitoleic acid
16:1
Stearic acid
18:0
Oleic acid
18:1
Linoleic acid
18:1
Linoleic acid
18:2
Linolenic acid
18:3
Describe a triglyceride
Glycerol backbone (C-C-C), fatty acid (ROOH)
How are triglycerides formed?
esterification
Glycerol + acid = mono glycerine + water
Cis fats
Double bonds, curved structure
Trans fats
Double bonds, straight structure
Omega-3 fat
Double bond at 3rd Carib from methyl end
How are trans fats formed?
partial hydrogenation
How does chain length affect melting point?
the longer the chain, the higher the melting point because of more interaction points
How does saturation affect melting point?
Greater unsaturation, the lower the melting point
Define plasticity
The ability to be moldable and still hold shape
What is hydrogenation
The process of converting unsaturated fats to saturated fats by adding hydrogen
What is interesterification
Heat and a catalyst to fats make it more homogenous, smaller crystals and higher quality
Define emulsion
Mixtures of water and fat/oil
2 examples of emulsions
Oil in water (mayonnaise), water in oil (margarine)
Explain emulsion formation
Energy and emulsifiers are needed
How do emulsions work?
Molecules have polar and nonpolar regions on 1 molecule
Natural emulsifying agents
Proteins, solid particles, phospholipids
Example of protein emulsifier
Hydrophilic and hydrophobic amino acids
Example of solid particle emulsifiers
Spices (usually temporary)
Example of phospholipid emulsifier
Lecithin in eggs
Synthetic emulsifying agents
Fatty acid esters, monoglycerides, diglycerides
3 types of emulsion instability
Coalescence, creaming, inversion
Coalescence
Merging of droplets
Creaming
Separation into 2 phases
Inversion
O/W to W/O
2 causes of emulsion instability
Film integrity (pH, agitation), droplet movement (heat, viscosity)
Describe egg white foams
Protein denatures, egg proteins surround air, hydrophobic towards air
What happens if you beat egg whites too much?
Dry, denatured proteins interact
What happens if you beat egg whites too little?
Transparent, not enough denaturing of proteins
How are whipped cream foams supported?
Cold temps, fat globules disrupted
State the order of relative sweetness and solubility of sugars
Fructose, sucrose, glucose, maltose, galactose, lactose
2 types of non enzymatic browning
caramelization and mallard reaction
Caramelization example and formation
Peanut brittle, no protein involved. Carb + dry heat (no moisture)
Maillard reaction example and formation
Bread/meat/caramels, includes protein, C=O + NH2
Define invert sugar
Sucrose broken into glucose and fructose by invertase or acid & heat
2 functions of invert sugar
Attracts more water, prevents crystallization
2 confection classifications
Crystalline, amorphous (chewy/hard)
Crystalline confection examples
Fudge, rock candy, fondant
Chewy amorphous confection example
Taffy, caramel
Amorphous hard confection example
Brittle, lollipop, butterscotch
What factors affect sucrose crystallization rate?
Temperature,concentration, agitation, interfering agents, seeding
How is sucrose crystallization prevented in crystalline confections?
Stirring while cold
How is sucrose crystallization prevented in non-crystalline confections?
Quick cooling
What are the 2 tests for candy doneness?
Boiling point, cold water test
Boiling point test
measures concentration of solutes in the syrup (objective)
Cold water test
Measures consistency, subjective
Define batter
Beaten, stirred, more water:flour
Define dough
Kneaded, less water:flour
Define gluten
Water insoluble protein complex with gluten in and gliadin
Define gliadin
fluid and sticky
Define glutenin
Elastic
How is gluten developed?
Hydration and physical manipulation
3 types of leavening gases
Air, steam, CO2
How is air incorporated into food?
Physically (beating, creaming, folding, whipping)
How is steam incorporated into food ?
Heat, water to steam
How is CO2 incorporated into food?
Chemical/biological reactions (baking powder/soda, yeast, bacteria)
Write the general reaction of baking soda with acid
NaHCO3 + H+ —> Na+ + H2CO3 + H2O + CO2
State the defects in baked goods containing too much baking soda
Too alkaline, soapy, color spots
State the defects in baked goods containing too little baking soda
Soggy, compact, whitened
State the ingredients of baking powder
25% baking soda, 25% starch, 25% dry acids
What is the action of slow acting acids?
Requires HEAT, is not soluble
What is a compound used as a slow acting acid?
sodium aluminum sulfate
What is the action of fast acting acids?
High soluble, does not require heat (can be done at room temperature)
What is a compound used as a fast acting acid?
Monocalcium phosphate monohydrate
What is the genus and species of yeast used in baked products?
Saccharomyces cerevisiae
What is the reaction of CO2 production via yeast
glucose --> ethanol + 2CO2
What are the 7 ingredients common to a baked product?
Flour, liquid, leavening agent, eggs, fat, salt, sugar
Flour function in baked products
Structure
Liquid function in baked products
hydration, steam, dissolver
Leavening agent function in baked products
texture
Eggs function in baked products
binding, emulsification
Fat function in baked products
Tenderness
Salt function in baked products
taste, leavening
Sugar function in baked products
taste, tenderness
3 purposes of manipulating ingredients in baked goods
distribute leavening, fat, and liquid
What factors affect optimum manipulation?
over/undermixing impacts gluten development
Define creaming
work sugar crystals into fat using air
Define cutting
Subdivide fat into flour (for layers)
Define folding
Gently incorporating 1 ingredient into another
Define kneading
stretch, fold, press dough to form gluten strands
Define whipping
Beating to add air
What are the essential ingredients in yeast bread?
Yeast, water, flour, salt
What steps are required for the straight dough method of manipulating yeast dough?
Punch step and proof step
What is the purpose of the punch step?
Gluten not overstretched, redistributes nutrients for yeast
What is the purpose of the proof step?
Allows for a 2nd rise, pH changes cause gluten changes
What is the muffin method of mixing?
Dry & liquids are mixed separately,
What is a quick bread?
no yeast, leavening is quick
Why is the muffin method used?
Gives the product enough gluten, but not too much to be tough. It also prevents tunnelling
How must cake ingredients be balanced?
Liquid (flour, egg) & dry (fat, sugar) ingredients are in equal proportions
How can a uniform texture be reached in shortened cake?
Creaming allows for more air pockets and an emulsifier evenly distributes the fat