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exothermic reaction + examples
releases energy (creating bonds > breaking them), eg self heating cans or combustion or respiration or neutralisation or rust
endothermic reaction + examples
takes in energy (breaking bonds > creating them), eg instant ice packs or photosynthesis or thermal decomposition
hydrogen fuel cell facts
harder to find places to refuel and far more expensive to refuel and manufacture, but no harmful waste products (only produces water) and more efficient
regular battery facts
more expensive than traditional petrol cars, but cheaper than hydrogen fuel cells. easy to recharge and not too expensive. relatively efficient
reactions in a hydrogen fuel cell
positive electrode: O2 + 2H2O + 4e- → 4OH-
negative electrode: 2H2 + 4OH- → 4H2O + 4e-
why are some batteries impossible to recharge
reversing current through battery does not reverse the reaction
reaction diagrams
initial energy as a straight line, curve upwards for activation energy and downwards for final energy. if final is higher than initial, endothermic. if initial is higher than final, exothermic. energy change is difference between initial and final, activation is difference between initial and the highest point
voltage + battery notes
difference in reactivity between metals at either end of the battery. electrons flow from more reactive → less reactive. the less reactive terminal is negative because electrons flow to it, so flow positive → negative
rechargable vs nonrechargable batteries
non are cheaper but worse for the environment, they fail when one reactant runs out and should be recycled but mostly go to landfill.
rechargables are more expensive, better for the environment, recharged by reversing current flow. they run out eventually. should be recycled