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Matter
The "stuff" of the universe.
States of matter
Solid - has definite shape and volume.
Energy
The capacity to do work (put matter into motion).
Types of energy
Kinetic - energy in action.
Forms of Energy
Chemical - stored in the bonds of chemical substances.
Energy Form Conversions
Energy is easily converted from one form to another.
Energy Questions
What form of energy is found in the food we eat?
Elements
Unique substances that cannot be broken down by ordinary chemical means.
Atoms
More-or-less identical building blocks for each element.
Atomic symbol
One- or two-letter chemical shorthand for each element.
Physical properties
Those detected with our senses.
Chemical properties
Pertains to the way atoms interact with one another.
Major Elements of the Human Body
Oxygen (O), Carbon (C), Hydrogen (H), Nitrogen (N).
Lesser elements
Make up 3.9% of the body and include Calcium (Ca), phosphorus (P), potassium (K), sulfur (S), sodium (Na), chlorine (Cl), magnesium (Mg), iodine (I), and iron (Fe).
Trace elements
Make up less than 0.01% of the body and are required in minute amounts, found as part of enzymes.
Nucleus
Consists of neutrons and protons.
Neutrons
Have no charge and a mass of one atomic mass unit (amu).
Protons
Have a positive charge and a mass of 1 amu.
Electrons
Found orbiting the nucleus, have a negative charge and 1/2000 the mass of a proton (0 amu).
Planetary Model
Electrons move around the nucleus in fixed, circular orbits.
Orbital Model
Regions around the nucleus in which electrons are most likely to be found.
Atomic number
Equal to the number of protons.
Mass number
Equal to the mass of the protons and neutrons.
Atomic weight
Average of the mass numbers of all isotopes.
Atomic number for H
1
Atomic number for He
2
Atomic number for Li
3
Mass number for H
1
Mass number for Ne
20
Mass number for Li
7
Isotope
Atoms with the same number of protons but a different number of neutrons.
Radioisotopes
Atoms that undergo spontaneous decay called radioactivity.
Molecule
Two or more atoms held together by chemical bonds.
Compound
Two or more different kinds of atoms chemically bonded together.
Mixtures
No chemical bonding takes place; can be separated by physical means.
Heterogeneous Mixture
A mixture that is not uniform in composition.
Homogeneous Mixture
A mixture that is uniform in composition.
Chemical Bond
An attraction between atoms that allows the formation of chemical substances.
Electron Shells
Energy levels that surround the nucleus of an atom.
Valence Shell
The outermost energy level containing chemically active electrons.
Octet Rule
Atoms interact to have eight electrons in their valence shell, except for the first shell which is full with two electrons.
Chemically Inert Elements
Elements that have their outermost energy level fully occupied by electrons.
Chemically Reactive Elements
Elements that do not have their outermost energy level fully occupied by electrons.
Ionic Bonds
Bonds formed between atoms by the transfer of one or more electrons.
Ions
Charged atoms resulting from the gain or loss of electrons.
Anions
Ions that have gained one or more electrons, developing a negative charge.
Cations
Ions that have lost one or more electrons, developing a positive charge.
Ionic Compounds
Compounds that form crystals instead of individual molecules.
Example of Ionic Compound
NaCl (sodium chloride).
Ionic Compound Example 1
MgCl2.
Ionic Compound Example 2
CaCl2.
Ionic Compound Example 3
KCl.
Covalent bonds
Covalent bonds are formed by the sharing of two or more electrons.
Electron sharing
Electron sharing produces molecules.
Single Covalent Bonds
A type of covalent bond where two atoms share one pair of electrons.
Double Covalent Bonds
A type of covalent bond where two atoms share two pairs of electrons.
Triple Covalent Bonds
A type of covalent bond where two atoms share three pairs of electrons.
Covalent Compounds
Examples include CH4, H2O, CO2, NH3, and O2.
Nonpolar molecules
Electrons shared equally between atoms produce nonpolar molecules.
Polar molecules
Unequal sharing of electrons produces polar molecules.
Electronegative atoms
Atoms with six or seven valence shell electrons are electronegative.
Electropositive atoms
Atoms with one or two valence shell electrons are electropositive.
Hydrogen Bonds
Too weak to bind atoms together
Chemical Reactions
Occur when chemical bonds are formed, rearranged, or broken
Chemical Equations
Written in symbolic form using chemical equations
Combination Reactions
Synthesis reactions which always involve bond formation
Decomposition Reactions
Molecules are broken down into smaller molecules
Exchange Reactions
Bonds are both made and broken
Oxidation-Reduction (Redox) Reactions
Reactants losing electrons are electron donors and are oxidized
Exergonic Reactions
Reactions that release energy
Endergonic Reactions
Reactions whose products contain more potential energy than did its reactants
Reversibility in Chemical Reactions
All chemical reactions are theoretically reversible
Factors Influencing Rate of Chemical Reactions
Temperature - chemical reactions proceed quicker at higher temperatures
Catalysts
Increase the rate of a reaction without being chemically changed
Enzymes
Biological catalysts
Biochemistry
Organic compounds contain carbon, are covalently bonded, and are often large
Inorganic Compounds
Do not contain carbon
Properties of Water
High heat capacity - absorbs and releases large amounts of heat before changing temperature
Salts
Inorganic compounds containing cations other than H+ and anions other than OH-
Acids
Release H+ and are therefore proton donors
Bases
Release OH- and are proton acceptors
Acidic Solutions
Have higher H+ concentration and therefore a lower pH
Alkaline Solutions
Have lower H+ concentration and therefore a higher pH
Neutral Solutions
Have equal H+ and OH- concentrations
Buffers
Systems that resist abrupt and large swings in the pH of body fluids
Carbonic Acid-Bicarbonate System
Carbonic acid dissociates, reversibly releasing bicarbonate ions and protons
Chemical Equilibrium
The chemical equilibrium between carbonic acid and bicarbonate resists pH changes in the blood