AP Chem unit 7

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13 Terms

1

Dynamic Equilibrium

Condition where the rate of the forward reaction equals that of the backward reaction.

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2

Equilibrium Constant (K)

A value that expresses the relationship between concentrations/partial pressures of reactants and products at equilibrium.

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3

Q

Indicates the extent to which a reaction has proceeded; compares reaction quotient with K to determine the direction shift.

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4

Q > K

Indicates there are too many products, causing the reaction to shift to the left (towards reactants).

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5

Q < K

Indicates there are too many reactants, causing the reaction to shift to the right (towards products).

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6

Le Châtelier’s Principle

Explains how a system at equilibrium responds to changes in concentration, temperature, volume/pressure, or dilution.

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7

Ksp

The equilibrium constant for the dissolution of an ionic solid.

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8

Qsp > Ksp

Indicates that a precipitate will form.

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9

Qsp < Ksp

Indicates that no precipitate is formed.

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10

Temperature Increase Effect on Equilibrium

Shifts the reaction towards the endothermic direction.

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11

Temperature Decrease Effect on Equilibrium

Shifts the reaction towards the exothermic direction.

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12

Reciprocal Relationship of K

When reversing a reaction, K becomes the reciprocal of the original K.

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13

Coefficient Multiplication Effect on K

If coefficients of a reaction are multiplied, K is raised to that power.

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