shit i need to memorize

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for chem 202 final

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53 Terms

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light speed (C) equals what??

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energy (E) equals what??

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paramagnetic

unpaired electrons

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diamagnetic

paired electrons

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atomic radius periodic trend

  • atomic radius increases as you go down a column

  • atomic radius decreases as you go across a period

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ionization energy periodic trend

  • ionization energy decreases as you go down a column

  • ionization energy increases as you go across a period

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electronegativity periodic trend

  • electronegativity decreases as you go down a column

  • electronegativity increases as you go across a period

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metallic character periodic trend

  • metallic character increases as you go diagonally down left on the periodic table

    • away from flourine

  • metallic character decreases as you go diagonally up right on the periodic table

    • towards flourine

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quantum numbers (n)

  • principal quantum number

  • s and p block??? literally just your row number

  • d block?? row number - 1

  • f block?? row number - 2

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quantum numbers (l)

  • azimuthal quantum number

  • n-1

    • or more if your n is higher

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quantum numbers (ml)

  • orientation quantum number

  • ± l

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quantum numbers (ms)

  • spin quantum number

  • ± ½

  • no right or wrong answer

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soluble ionic compounds and exceptions

  • NO3- : always soluble, no exceptions

  • C2H3O2- : always soluble, no exceptions

  • Cl-, Br-, I- (group 17’s) : not soluble with Ag+, Hg22+, and Pb2+

  • SO42- (sulfate) : not soluble with Sr2+, Ba2+, Hg22+, and Pb2+

  • NH4+

  • alkali metals (group 1)

  • alkali earth metals (group 2)

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insoluble ionic compounds and exceptions

  • S2- : soluble with NH4+, alkali metals, Ca2+, Sr2+, and Ba2+

  • CO32- and PO43- : soluble with NH4+ and alkali metals

  • OH- : alkali metals, Ca2+, Sr2+, Ba2+

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breaking bonds

  • REQUIRES ENERGY

  • endothermic

  • (+) delta H

  • on the “reactants” side of the reaction

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building bonds

  • RELEASES ENERGY

  • exothermic

  • (-) delta H

  • on the “products” side of the reaction

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nonpolar

0-0.5

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polar covalent

0.5-1.6

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ionic

1.6-2

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linear

  • electron geometry: linear

  • molecular geometry: linear

  • 2 electron binding sites

  • 2 bonds

  • 0 lone pairs

  • 180 degrees bond angles

  • ex: CO2

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trigonal planar

  • electron geometry: trigonal planar

  • molecular geometry: trigonal planar

  • electron binding sites: 3

  • 3 bonds

  • 0 lone pairs

  • 120 degree bond angles

  • ex: BCl3

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bent (trigonal planar)

  • electron geometry: trigonal planar

  • molecular geometry: bent

  • electron binding sites: 3

  • 2 bonds

  • 1 lone pair

  • less than 120 degree bond angles

  • ex: SO2

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tetrahedral

  • electron geometry: tetrahedral

  • molecular geometry: tetrahedral

  • electron binding sites: 4

  • 4 bonds

  • 0 lone pairs

  • 109.5 degree bond angles

  • ex: CH4

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trigonal pyramidal

  • electron geometry: tetrahedral

  • molecular geometry: trigonal pyramidal

  • electron binding sites: 4

  • 3 bonds

  • 1 lone pair

  • 107.5 degree bond angles

  • ex: PH3

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bent (tetrahedral)

  • electron geometry: tetrahedral

  • molecular geometry: bent

  • electron binding sites: 4

  • 2 bonds

  • 2 lone pairs

  • 104.5 degree bond angles

  • ex: H2O

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trigonal bipyramidal

  • electron geometry: trigonal bipyramidal

  • molecular geometry: trigonal bipyramidal

  • electron binding sites: 5

  • 5 bonds

  • 0 lone pairs

  • 120 degree equatorial bond angles

  • 90 degree axial bond angles

  • ex: PCl5

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seesaw

  • electron geometry: trigonal bipyramidal

  • molecular geometry: seesaw

  • electron binding sites: 5

  • 4 bonds

  • 1 lone pair

  • less than 120 degree equatorial bond angles

  • less than 90 degree axial bond angles

  • ex: SF4

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t-shaped

  • electron geometry: trigonal bipyramidal

  • molecular geometry: t-shaped

  • electron binding sites: 5

  • 3 bonds

  • 2 lone pairs

  • less than 90 degree bond angles

  • ex: ClF3

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linear (trigonal bipyramidal)

  • electron geometry: trigonal bipyramidal

  • molecular geometry: linear

  • electron binding sites: 5

  • 2 bonds

  • 3 lone pairs

  • 180 degree bond angles

  • ex: XeF2

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octahedral

  • electron geometry: octahedral

  • molecular geometry: octahedral

  • electron binding sites: 6

  • 6 bonds

  • 0 lone pairs

  • 90 degree bond angles

  • ex: SF6

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square pyramidal

  • electron geometry: octahedral

  • molecular geometry: square pyramidal

  • electron binding sites: 6

  • 5 bonds

  • 1 lone pair

  • less than 90 degree bond angles

  • ex: BrF5

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square planar

  • electron geometry: octahedral

  • molecular geometry: square planar

  • electron binding sites: 6

  • 4 bonds

  • 2 lone pairs

  • 90 degree bond angles

  • ex: XeF4

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solution is what

solute and solvent mixed together

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molarity (M)

<p></p>
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molality (m)

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mole fraction (X)

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mol percent (mol %)

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parts by mass (%)

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raoult’s law (non-volatile, non-electrolyte)

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raoult’s law (volatile, non-electrolyte)

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raoult’s law (volatile?, electrolyte)

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calculating change in freezing/boiling point

b/c of electrolytes (raoult’s law sorta)

<p>b/c of electrolytes (raoult’s law sorta)</p>
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henry’s law

converts atm to molarity basically

<p>converts atm to molarity basically</p>
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osmotic pressure equation

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all those extra Ecell and delta G equations for electrochem and delta G

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alpha decay particle

  • highest ionization power

  • lowest penetrating power

  • always released

<ul><li><p>highest ionization power</p></li><li><p>lowest penetrating power</p></li><li><p>always released</p></li></ul><p></p>
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beta decay particle

  • literally an electron

  • mid ionization power and penetrating power

  • BETA DECAY IS RELEASED OF ELECTRON

  • a neutron converts into a proton and an electron basically

<ul><li><p>literally an electron</p></li><li><p>mid ionization power and penetrating power</p></li><li><p>BETA DECAY IS RELEASED OF ELECTRON</p></li><li><p>a neutron converts into a proton and an electron basically</p></li></ul><p></p>
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gamma emission

  • literally just light

    • no mass or charge

  • lowest ionization power

  • highest penetrating power

  • releases light (gamma radiation) b/c an element(?) is “meta stable” and needs to chill out

<ul><li><p>literally just light</p><ul><li><p>no mass or charge</p></li></ul></li><li><p>lowest ionization power</p></li><li><p>highest penetrating power</p></li><li><p>releases light (gamma radiation) b/c an element(?) is “meta stable” and needs to chill out</p></li></ul><p></p>
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meta stable

element is too excited and needs to release gamma radiation in order to stabilize/chill out

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positron particle and emission

  • literally an “anti-electron”

  • they get released

<ul><li><p>literally an “anti-electron”</p></li><li><p>they get released</p></li></ul><p></p>
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electron capture

  • literally beta decay just in reverse

  • an electron is CAPTURED

<ul><li><p>literally beta decay just in reverse</p></li><li><p>an electron is CAPTURED</p></li></ul><p></p><p></p>
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subatomic particles notation

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