8A Alkyne Reaction Strategies
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21 Terms
Hydrohalogenation reagents
2 moles HI/HBr/HCl
Hydrohalogenation regiochemistry
Markovnikov
Hydrohalogenation stereochemistry
N/A
Hydrohalogenation product
more substituted dihalide
Hydrohalogenation w/ peroxide reagents
2 moles HX, ROOR
Hydrohalogenation w/ peroxide regiochemistry
anti-Markovnikov
Hydrohalogenation w/ peroxide stereochemistry
N/A
Hydrohalogenation w/ peroxide product
less substituted dihalide
Halogenation reagents
2 moles BR2/Cl2
Halogenation regiochemistry
N/A
Halogenation stereochemistry
N/A
Halogenation product
tetrahalide
Hydromercuration reagents
HgSO4, H2SO4, H2O
Hydromercuration regiochemistry
Markovnikov
Hydromercuration stereochemistry
N/A?
Hydromercuration product
ketone
Hydroboration/Oxidation reagents
1. BH3-THF
2. H2O2, -OH
Hydroboration/Oxidation regiochemistry
anti-Markovnikov
Hydroboration/Oxidation stereochemistry
??
Hydroboration/Oxidation product
aldehyde
Enol intermediate
Hydromercuration and Hydroboration