Unit 6: Thermodynamics (copy)

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25 Terms

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Exothermic

________ is when energy is transferred from the system to the surroundings, such as when a chemical reaction occurs in a beaker and the beaker feels hot.

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Hess’s Law

________ states that if a reaction can be broken into a series of steps, the sum of the ΔH of those steps are equal to the ΔH of the reaction.

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Enthalpy change

________ is the measure of energy that is released or absorbed when bonds are broken /formed.

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Temperature

________ remains constant during a phase change.

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Calorimetry

________ is the measurement of heat changes during a chemical reaction.

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Enthalpy of vaporization

________ is how much energy is required to turn a liquid to a gas.

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Endothermic reactions

________ occur when a system absorbs the energy from the surroundings, such as when a beaker feels cold.

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Vapor pressure

________ is the amount of pressure given off by molecules as they go from solid /liquid to gas.

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heat of vaporization

The ________ is the energy given off when a gas condenses.

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Hydration energy

________ is a Coulombic energy and its magnitude increases as the ions increase their charge or decrease the size.

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released

When bonds are formed, energy is ____.

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Enthalpy of fusion

________ is the amount of energy required to cause a solid to melt.

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absorbed

When bonds are broken, energy is _____.

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Solid to gas

sublimation

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Gas to solid

deposition

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ΔH

Enthalpy change

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ΔHf°

Enthalpy of formation

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Enthalpy of formation

The amount of energy released when one mole of a compound is made from pure substances

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Vapor pressure

Molecules that go from solid/liquid to gas emit ________.

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Endothermic

________ is when energy is transferred from the surrounding to the system, such as when a chemical reaction occurs in a beaker and the beaker feels cold.

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Enthalpy of formation of O2

Zero

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Enthalpy of formation of graphite

Zero

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Enthalpy of formation of diamond

1.9 kJ / mole

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Bimolecular

elementary reaction with two particles

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Nature of reactant

Reaction between simple ions are usually instataneous