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Entropy (S)
A measure of the distribution of available energy among particles, showing how disordered the system is. Higher entropy means the system is more stable
Increase in entropy means…
more disorder, for example solid to gas
ΔS=
Sproducts - Sreactants
Gibbs equation
ΔG = ΔH – TΔS
ΔG in kJ/mol, ΔH in kJ/mol, T in K, ΔS in kJ/K/mol
A reaction is spontaneous when…
Gibbs free energy has a negative value
A reaction is not spontaneous when…
Gibbs free energy has a positive value
If the value of K is greater than 1…
The products are favoured, the equilibrium lies to the right
If the value of K is less than 1…
The reactants are favoured, the equilibrium lies to the left