R1.4 Entropy and spontaneity

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8 Terms

1
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Entropy (S)

A measure of the distribution of available energy among particles, showing how disordered the system is. Higher entropy means the system is more stable

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Increase in entropy means…

more disorder, for example solid to gas

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ΔS=

Sproducts - Sreactants

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Gibbs equation

ΔG = ΔH – TΔS

ΔG in kJ/mol, ΔH in kJ/mol, T in K, ΔS in kJ/K/mol

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A reaction is spontaneous when…

Gibbs free energy has a negative value

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A reaction is not spontaneous when…

Gibbs free energy has a positive value

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If the value of K is greater than 1…

The products are favoured, the equilibrium lies to the right

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If the value of K is less than 1…

The reactants are favoured, the equilibrium lies to the left