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Ecosystem
a geographic area where plants, animals, and other organisms, as well as weather and landscape, work together to form a bubble of life
Systems Approach
The breaking down of a complex concept into smaller units for purpose of a better understanding of the whole
Regulation
An authoritative rule dealing with details or procedure.
A rule or order issued by an executive authority or regulatory agency of a government and having the force of law.
RCRA (Resource Conservation and Recovery Act)
public law that creates the framework for the proper management of hazardous and non-hazardous solid waste
Ethics
Moral principles that govern a person's behavior or the conducting of an activity
Silent Spring
1962 book by Rachel Carson revolutionized Environmentalism and kick-started the modern environmental movement. Condemned the overuse of pesticides including DDT.
Stoichiometry
the measure of elements
Reactants
A starting material in a chemical reaction
Products
The elements or compounds produced by a chemical reaction.
Chemical Equilibrium
a state in which there is no chemical driving force favoring a change in the system'scomposition
Equilibrium Constant
The rate at which a reaction moves one way or another
Solubility
the maximum quantity (mass) of a substance (solute) that can dissolve in a unit volume of solvent under specified conditions
Acid-Base Equilibria
all inorganic compounds and many organic compounds can be classified as acids, bases, or salts
Henry's Law
the mass of a gas that dissolves in a definite volume of liquid is directly proportional to the pressure of the gas
Reaction Order
Describes how the rate of a chemical reaction depends on reactant concentration.
Concentration Units
Milligrams per Liter (mg/L)
Parts per million (ppm)
Percent (by weight)
Normality (N)
Types of chemical reactions
Combustion: Reaction with oxygen, producing heat.
Oxidation-Reduction (Redox): Electron transfer reactions.
Acid-Base Neutralization: Acid + Base → Salt + Water.
Reaction Kinetics
Studies the rate of chemical reactions and factors affecting them (e.g., temperature, catalysts).
Organic Compounds
Carbon-based molecules, including hydrocarbons, alcohols, and amino acids.
Water Chemistry
The study of a polar molecule, which is a good solvent, with pH 7
Historical view of Henry's Law
(1803) proposed at the beginning of the era of modern chemistry, which is surprisingly early, and the law remains very popular. Can be expanded using the first and second law of thermo dynamics.
Great Spheres
Lithosphere,
Biosphere
Atmosphere
Hydrosphere
Cryosphere
Lithosphere
A rigid layer made up of the uppermost part of the mantle and the crust.
biosphere
part of land water and air that contains life.
Atmosphere
A thin layer of gases surrounding Earth
Hydrosphere
All the water at and near the surface of the earth, 97% of which is in oceans
Cryosphere
A term referring to all water that is temporarily frozen in polar ice caps, snow, permafrost, and glaciers
Abiotic
non-living components of an environment
Four main classes of biological compounds
Carbohydrates
Nucleic Acids
Proteins
Lipids
Carbohydrates
major source of energy, the most abundant class of organic compounds found in living organisms
Nucleic Acids
Store and transmit hereditary information that makes up the DNA any organism
Proteins
Called the building blocks of life and found in every organism on Earth. They are the most common molecules found in cells.
Lipids
provide energy for cells, create the cel structure, and provide insulation for the cell.
Viruses
they have genes, they reproduce, and they evolve through natural selection. They do not have cells, they cannot turn food into energy, and without a host they are just inert packets of chemicals Half of human DNA came from these.
Catabolic Pathways
sequence of chemical reactions that break down complex molecules into smaller units and release energy
Energy
all organisms require a constant supply of
Importance of photosynthesis
all life on earth , either directly or indirectly, depends on photosynthesis as a source of food, energy , and O2
Catabolic Pathways
Aerobic Respiration
Anaerobic Respiration
Fermentation
pathogen
is a micro-organism that has the potential to cause disease
infection
is the invasion and multiplication of pathogenic microbes in an individual or population
Disease
is when the infection causes damage to the individual's vital functions or systems
Biological Water treatment
involves the use of different microorganisms; bacteria, viruses, and protozoa
Waterborne diseases
are caused by pathogenic microorganisms that most commonly are transmitted in contaminated fresh water.
cholera and typhoid, are the diseases that are transmitted through drinking water
Water-washed (water-scarce) diseases
diseases where the interruption of the transmission is achieved through proper attention to effective sanitation, washing and personal hygiene
Water-based diseases
diseases transmitted by contact with water, e.g., recreational swimming.
Water-vector diseases
such as malaria, are diseases that are transmitted by a vector, such as the mosquito, which needs water or moisture in order to breed
Law of Conservation of Matter
Matter is not created nor destroyed in any chemical or physical change
Inputs
= outputs + accumulation
Outputs
= inputs - accumulation
Accumulation
= inputs - outputs
Steady State (condition)
when the rate of input and the rate of output are constant and equal, then the mass rate of accumulation is zero
Conservative Substance or Compound
no loss, no formation, mass is conserved - what goes in equals what goes out
decay
(or transformation) is usually time dependent,so a reaction rate is associated
Flowrate
Q given in units (volume/time)
Mixed Systems
Every drop of fluid within the system contains the same concentration of materials and has the same physical properties
Non-conservative
When substance of interest is not conserved
completely mixed batch reactor (CMBR)
Materials are added to a tank, mixed for a sufficiently long period of time for the desired reaction to takeplace, and then discharged as a "batch"
Open system
is one in which both energy and matter can flow across the boundary
Closed system
is one in which energy can flow across the boundary but matter cannot
Specific heat
the amount of energy needed to raise the temperature of a unit mass of a substance by 1 degree
British Thermal Unit (BTU)
The amount of heat required to raise the temperature of one pound of water by one degree Fahrenheit
Kilocalorie
energy required to raise 1 kg of water by 1 degree C
Enthalpy
Internal energy of a system plus the product of the pressure and volume of the system
Internal Energy
is equal to the net heat energy entering the system minus the net work done by the system
phase change
When a substance changes phase, energy is absorbed or released without a change in temperature
Heat transfer
Conduction
Convection
Radiation
Conduction
Takes place when there is direct physical contact between objects.Usually associated with solids , where the rate of heat transfer is proportional to the thermal conductivity of the material
Convection
Occurs when a liquid or gas atone temperature comes in contact with a substance at another temperature
Radiation
Can take place even in the absence of any physical medium between objects
Energy Balances
Practice of the first law of thermodynamics
Plug Flow System
theoretically the opposite ofa completely mixed system...an un-mixed system... however the volume for the system under consideration can be considered constant
Plug Flow Reactor (PFR)
Reactions can still take place when non-conservative substances are involved
Step function response
When the concentration of a substance ofi nterest entering a flow-through system changes suddenly, the result of this change of concentration
First Law Thermo
Energy cannot be created or destroyed
Forms of Energy
kinetic energy and potential energy
Producers
organisms that take in and use energy from the Sun or some other source to produce food
Consumers
organisms that take in energy when they feed on producers or other consumers
Decomposers
organisms that take in energy as they break down the remains of organisms
Food Chain
cycle of life with prey and predators
Trophic Levels
producers, primary consumers, secondary consumers, tertiary consumers etc.
Eutrophication
the process by which a body of water becomes enriched in dissolved nutrients that stimulate the growth of aquatic plant life usually resulting in the depletion of dissolved oxygen
Sulfur Cycle
Similar to water, Sulfur is emitted into the air rained down dissolved in water. Sulfur water then enters groundwater where plants and decomposition absorb the sulfur.
ways humans impact ecosystems
Human activities can accelerate the rate at which nutrients enter an ecosystem.
Runoff from agriculture and development, pollutionfrom septic systems and sewers, and other human-related activities increase the flux of both inorganicnutrients and organic substances into terrestrial,aquatic, and coastal marine ecosystems
Bioaccumulation
Contaminate increases in one species over time
Biomagnification
Contaminate increase effect as it goes up the food chain
Nutrient Cycles
Carbon Cycle
Nitrogen Cycle
Phosphorus Cycle
Sulfur Cycle
Population Dynamics
A branch of knowledge concerned with the sizes of populations and the factors involved in their maintenance, decline, or expansion
What is the Systems Approach?
A framework used in engineering and science to break complex systems into smaller parts for better understanding and management. In environmental engineering, it applies to water, air, and solid waste management systems
Issues facing the ecosystem:
Population growth
Pollution (air, water, land)
Climate change
Deforestation & biodiversity loss
Waste disposal
Depletion of natural resources
Why are regulations needed?
Pollution and environmental destruction led to health risks and ecosystem damage. Without regulations, industries did not always self-police. Laws like the Clean Air Act, Clean Water Act, and RCRA help protect resources.
Top 5 Environmental Regulations
#1 - Reorganization Plan No.3 of 1970
#2 Clean Air Act (1970)
#3 - Clean Water Act. (1972) The Federal Water Pollution Control Act of 1948, after
being heavily amended, became the Clean Water Act in 1972
#4 – Endangered Species Act (1973)
#5 – Montreal Protocol. (1987) International treaty signed by the U.S. in 1987. Signed by 197 countries
ablished in 1970