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gas
a substance that has neither definite volume nor definite shape.
characteristics of gasses
expand to fill their containers
are highly compressible
have extremely low densities
form homogenous mixtures
molecules in a gas are relatively far apart
vapors gaseous state of any substance that normally exists as a liquid or solid
pressure
P = F/A (force over area)
produced by gas molecules colliding with the walls of a container
determined by the frequency & force of collisions
increased pressure is due to:
more frequent collisions
higher energy
Pressure depends on:
Volume of the gas
Number of gas molecules
Temperature of the gas
How does decreasing the volume of the gas
affect its pressure?
Decreasing the volume of the gas increases its
pressure because the gas molecules are
crowded into a smaller volume and collide with
the container walls more frequently.
Pressure is proportional to ____
n (number of molecules) at constant Temp. and Volume.
How does more moles affect the pressure?
Frequency of collision increases with more moles of gas in the container.
Atmospheric pressure
The force exerted by the atmosphere on a given surface area.
Applies a force equally in all
directions
Decreases with an increase in
altitude
barometer
An instrument that measures atmospheric pressure
mm Hg to torr
1 mm Hg = 1 torr
atm to torr
1 atm = 760 torr
atm to pascal
1 atm = 101,325 Pa
the 4 variables that define the physical states of gases:
• Pressure
• Temperature
• Volume
• Number of Moles of Gas
volume and pressure relationship
Pressure and Volume are inversely proportional.
Decreasing volume causes pressure to increase, and vice-versa.
This is referred to as Boyle's Law.
volume and temp relationship
Volume and Temperature are directly proportional.
When one increases, so does the other. (As you heat something, it tends to expand.)
This is referred to as Charles's Law.
Absolute Zero
The temperature at which all motion stops
0K or -273OC
The number of moles of gas and the volume they occupy are directly proportional. (The more gas you have, the more space it occupies, at constant pressure and temperature.)
This is referred to as Avogadro's Law.
STP
Standard Temperature and Pressure
P = 1 atm
T = 273K
n = 1 mole
ideal gas equation
PV = nRT
P
pressure (atm)
V
volume (Liters)
n
R
gas constant (0.08206 atmL/Kmol)
T
temperature (kelvins)
grams to moles
divide by molar mass
celsius to kelvin
C+273
torr to atm
760 torr = 1 atm
how to solve gas law problems
1) Identify which of the four variables are changing.
2) Put all the "constants" on one side and the variables that are changing on the other.
3) Rewrite the equation with the variables on both sides of the equal sign. Apply subscripts of "1" to one side and "2" to the other.
4) Figure out what is given and what is needed, solve for needed.
5) PUT NUMBERS IN LAST