Ochem Synthetic Transformations

Reagents for oxymercuration (8.1)?

1. Hg(AcO)2, H2O, TFN (solvent)

2. NaBH4

what i

reactant of oxymercuration?

What is the reaction and mechanism of oxymerucration (8.1)?

reagents for alkoxymercuration (8.2)?

1. Hg(AcO)2, HOR, THF

2. NaBH4

product of alkoxymercuration (8.2)?

reactant of alkoxymercuration (8.2)?

mechanism for alkoxymercuration (8.2)?

reagents for anti-markinow addition of H and OH (8.3)?

1. BH3, THF

2. H2O2, NaOH, water (solvent)

product of 8.3?

reactant of 8.3?

8.3 mechanism?

reagents for anti-markinov Br (8.4)?

HBr, peroxides, heat or light

product of 8.4?

reactant of 8.4?

8.4 mechanism?

Reagents for addition of H and X Markov (8.5)

HX, no peroxides, cold and dark

product of 8.5?

reactant of 8.5?

8.5 mechanism?

reagents of oxidation of an alkene to an epoxide (9.2)?

MCPBA

products of 9.2?

reactant of 9.2?

9.2 mechanism

reagents of addition of br2 to alkene (9.1)

Br2

product of 9.1?

reactant of 9.1?

9.1 mechanism?

reagents of anti-markov epoxide ring opening (9.3)?

1. strong base

2. dilute acid

product of 9.3?

reactant of 9.3?

9.3 mechanism?

reagents for Markov epoxide ring opening (9.4)?

1. H+, HOR

product of 9.4?

9.4 reactant?

9.4 mehcanism?

reagents for Markov addition of Br and OR (9.5)?

Br2, HOR, R

product for 9.5?

9.5 reactant

9.5 mechanism?

reagents for cycloprpane ring from an alkene (9.6)?

CHCl3, KOH

product of 9.6?

9.6 reactant?

9.6 mechanism?