ch 12 ochem review
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rxns memorization
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15 Terms
Making Ether
Alkoxymercuration-reduction (ALKENE+ Hg(OAC)2 + EtOH + REDUCTION→)
Making Ether
Alkene +H2SO4 + MeOH
Making epoxide
William ether synthesis (halohydrin (alkane (OH & Br group) + NaH )
Making epoxide
Alkene + Proxy acid (RCO3H)
Making epoxide
Alkene→ Br2 & H2O→base (OH-, NaH, etc)
Breaking epoxide
Epoxide+ EtOH in NaOEt solvent
Breaking epoxide
Grignard (-MgBr) + H3O+
Breaking epoxide
Epoxide + EtOH in H2SO4 (O accepts H from S. acid)
Making Ether
Williamson ether synthesis (R-OH+ R-X)
Breakin ether
Strong acids (HI, HCl, HBr, Etc. [SN2 if primary C] [SN1 if tertiary C])
Making diol
Alkene + RCO3H + H3O
Breaking diol
H5IO6 (creates ketones & aldehydes by making c-c bonds where there OH groups)
Making Diol
Alkene + OsO4
Making Diol
Alkene + KMnO4 (Cis diol)
Making Ether
Industrial prep (EtOH +H2SO4→EtO2)
Note 
Flashcards (25)