Chemistry Thermochemistry quiz

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16 Terms

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What is heat?

Energy transferred between two substances due to a temperature difference. Flows from higher to lower temperature. SI Unit: Joules (J).

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What is specific heat?

  • The energy required to raise the temperature of 1 g of a substance by 1°C. Specific Heat of Water: 4.18 J/g°C4.18J/g°C.

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What are endothermic?

Endothermic: Uses heat(+ΔH)

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exothermic reactions?

Releases heat (-ΔH)

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What is entropy?

A measure of disorder in a system.

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Factors affecting entropy:

  • Temperature: Higher temp = more disorder.

  • State of Matter: Gases > Liquids > Solids.

  • Number of Molecules: More molecules = more entropy.

  • Types of Molecules: More varied substances = more entropy.

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What is Gibbs Free Energy?

The amount of energy available to do work

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Gibbs Free Energy formula?


ΔG=ΔH−TΔS

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Negative ΔH and Positive ΔS.

Always Spontaneous

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Positive ΔH and Negative ΔS.

Never Spontaneous

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Negative ΔH and Negative ΔS.

Low Temp Spontaneity

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Positive ΔH and Positive ΔS.

High Temp Spontaneity

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How to calculate enthalpy by heats of formation?

ΔHHf(Products)−ΣHf(Reactants).

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How to calculate enthalpy by Bond Energies:

ΔH=(Bonds Broken)−(Bonds Formed).

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How to calculate enthalpy by Hess’s law?

Combine enthalpy changes from multiple reactions.

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What is activation energy?

Activation Energy (EA): The minimum energy required for a reaction to occur.