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Waxes
Are composed of high molecular weight organic molecules. Dental waxes are composed of natural and synthetic waxes, gums, fats, fatty acids, oil, natural and synthetic resins and pigments
Pattern wax
= models of a restoration or appliance a.inlay wax b.baseplate wax C.casting
Processing wax
auxiliary materials in production of casts; extension of impression trays; or in soldering
a. boxing wax
b. utility wax
c. sticky wax
d. carving wax
e. block-out wax
Impression wax
impression materials. Recently, light-cured resin pattern materials have become available.
a. corrective wax
b. bite registration wax
Type 1
medium wax for direct wax patterns in the mouth.
Type II
softer wax used in indirect technique in inlays and crowns fabrication. Generally in blue, green, or purple rods or sticks about 7.5 cm long and 6 mm in diamond
Excess residue
after melting, it is essential that no excess residue remain in the investment mold form to cause incomplete casting of the margins of the restorations. The speciation limits the nonvolatile residue of inlay waxes to a maximum of 0.10%.
Flow
highly dependent on temperature, composition of the wax, force causing deformation, and length of time that the force is applied. Greatly increases as the melting range of the wax is approached or as the load and its length of application are increased.
Thermal expansion
waxes expand when heated and contract when cooled. In general, dental waxes have the largest values of coefficient of thermal expansion of any material used in dentistry
Type 1 - The maximum allowable expansion (or shrinkage when the wax cools) between 25-30C and 25-37C is
0.20% and 0.60%
Residual stresses
Stress remaining in a wax as a result of manipulation is residual stress.
Casting Wax
for the pattern for metallic framework of RPD and other structures
Baseplate Wax
used on the baseplate tray to establish the vertical dimension, the plane of occlusion etc. for CD construction.
Boxing Wax
for forming a plaster of working cast from an impression, a wax box must be formed around the impression prior to cast construction
Utility Wax
used to reline a tray for impression; done to prevent sag and distortion of the impression material. Consists largely of beeswax, petrolatum and other soft waxes. In ortho, known as periphery wax.
Sticky Wax
used to assemble metallic resin pieces in a fixed temporary position
Bite Registration Wax
used to articulate accurately certain models of opposing quadrants. Made from 28- gauge casting wax
Steps in Inlay Construction
1.Construction of a wax pattern
Spruing
Withdraw wax pattern from cavity
. Washing wax pattern with wetting agent (denatured alcohol)
Investing
Place asbestos strip inside inlay ring
Position bur
Mix investment compound and pour inside the inlay ring to overfill
For high-fusing gold and non-precious alloys, Phosphate-bonded investments are used instead of gypsum investments
Expansion of the investment
. The investment is allowed to set in air for at least 45 minutes.
Wax elimination or burnout
Casting the alloy
Quenching
Pickling
Polishing after pickling
Fitting of the inlay inside the cavity.
Cementing
Spruing
forms a channel a channel for elimination of wax during burn-out & for molten alloy to enter the mold space;; a short pin known as the sprue is attached to the thickest portion of the wax pattern.
Washing wax pattern with wetting agent (denatured alcohol)
to remove oil for better adhesion of investment compound to the surface of the wax.
Investing
a. P/W 15g/ 7cc of water, construct a cherry or core using brush technique
Place asbestos strip inside inlay ring
; a cushion as the investment compound expands. Must have a clearance of 1/8 inch or 3 mm from top of ring
Position bur
(sprue pin) with cherry on the crucible former then place inside inlay ring. Must have a clearance of ¼ inch or 6mm from top of ring
Mix investment compound and pour inside the inlay ring to overll.
The investment material has a binder, calcium sulfate hemihydrate and the refractory is either quartz or cristobalite, which are forms of silica.
*For high-fusing gold and non-precious alloys,
Phosphate-bonded investments are used instead of gypsum investments.
Expansion of the investment
It is used to compensate for the shrinkage of the gold casting as it cools during the casting procedure. A total of 1.5% to 2% mold expansion is the aim in most gold castings. During the setting of the investment, an expansion of 0.25% takes place because of the gypsum crystallization process.
45
The investment is allowed to set in air for at least ?? minutes.
Wax elimination or burnout
The mold is placed in a burnout oven with the sprue hole facing downward to facilitate outward ow of the molten wax for 30 minutes, temperature of 482 C – 650 C
Casting the alloy
gold alloys may be melted for casting by the use of a gas-air blow torch or in an electric casting machine.
Quenching
After the casting machine stops rotating, the mold is removed and quenched in water and casting is recovered by breaking away the investment mold.
Pickling
The casting is pickled in acid after casting to remove the surface oxidation that gives it a dark appearance.
Polishing after pickling
is done with the use of abrasive wheels, rubber wheels, pumice, Tripoli and finally, rouge.
Dental Porcelain
a mixture of FELDSPAR (main constituent), QUARTZ, & metallic oxides
The compressive strength of a porcelain restoration is _______ than it's tensile or shear strengths.
Greater
Brittle
Dental porcelain restorations are _______ and are not capable of much plastic deformation.
Quartz
a strengthener.
Aluminous Porcelain
uses alumina instead of quartz as a strengthener. This porcelain is considerably stronger than conventional porcelains.
Kaolin
a clay and sticky material that binds the particles together when the porcelain is "green" or unfired.
Silicone Dioxide (64-6(%)
Aluminum Oxide (8-19%)
Potassium oxide (8%)
Sodium oxide (2-5%).
Constituents of Dental Porcelain
a. Be low-fusing temperature.
b. High viscosity
c. Resistance to devitrification (crystallization)
Dental porcelain used in fabricating restorations MUST have these properties
High Fusing Porcelains
Medium Fusing
Low Fusing
3 classes of dental porcelain
High fusing porcelains
used to manufacture DENTURE TEETH.
Medium fusing
used for all-ceramic and porcelain jacket crowns. § Components: oxides of lithium, magnesium, and phosphate (in addition to silicone dioxide, aluminum oxide, potassium oxide, and sodium oxide).
Low fusing
used for metal-ceramic (PFM) crowns.
Aluminum oxide
increase its resistance to "slumping down" during firing.
Calcium oxide
- also added to low-fusing porcelains.
DEGASSING (HEAT TREATMENT)
the process by which a casting is heated in a porcelain furnace to a temperature of 980°C to burn off any remaining impurities prior to adding porcelain.
Composition
Fabrication Method
WAYS TO CLASSIFY ALL-CERAMIC CROWNS
Feldspathic porcelain
used for conventional porcelain-jacket crowns.
Aluminous porcelain
- found in Vitadur, Hyceram, Cerestore, & Inceram systems.
Alumina
is used to reinforce glass. Porcelain strength is determined by the amount of alumina reinforcement
Low Bisque Firing
Medium Bisque Firing
High Bisque Firing
3 stages involved in firing dental porcelain
Low bisque firing
Particles lack complete adhesion; low amount of shrinkage occurs and very porous
Medium bisque firing
: Water evaporates with better cohesion to powder particles and some porosity.
High bisque firing
Fusion of particles to form a continuous mass, complete cohesion and no more shrinkage.
GLAZED PORCELAIN
It is non-porous, resists abrasion, possesses esthetic ability, and is well tolerated by the gingiva.
OVER GLAZES (APPLIED GLAZES)
It is a ceramic powder that may be added to a porcelain restoration after it has been fired.
0.7 mm
(Metal Ceramic Restorations) The absolute minimum required thickness of the porcelain is
0.3 - 0.5 mm for high noble gold alloys, 0.2 for base metal alloys
Metal coping thickness can vary from
.5mm, 1.0mm
For metal ceramic crown, it is required to create space for ____ mm of metal + ____ of porcelain
inadequate condensation of the porcelain
The most common cause of porosity in the porcelain is
green discoloration
Porcelain baked onto a high-fusing gold alloy may exhibit a
High-gold noble alloy
Palladium-Silver alloys
Nickel-Chromium alloys (base metal alloys):
PFM ALLOYS: