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Dimitri Mendeleev
Had elements arranged in order of increasing atom mass show similar chemical and physical properties
This occurs at periodic intervals
Modern Periodic Law: the physical and chemical properties of elements are periodic functions of their atomic numbers
Periods
Horizontal rows, the number of the period indicates the highest principal energy level with electrons(shells)
Groups(families)
vertical columns on periodic table
sum number of valence electrons means
similar properties
metals general definition
elements located to the left of the staircase(75% of the table)
metalloid general definition
elements adjacent to the staircase(excluding Al)
nonmetals general definition
elements located to the right of the staircase
common properties of metals
solids at room temperature(excluding Hg)
malleable
ductile
have luster
good conductors of heat and electricity because of highly mobile valence electrons
low ionization energy
low electronegativity values
need to lose electrons to form positive ions(cations) with smaller radii
Why do metals conduct electricity?
valence electrons in metals move freely throughout the structure
properties of nonmetals
many are gases at room temperature(bromine is a liquid)
some are network solid like diamond
brittle
solids are dull
poor conductors of heat and electricity
high ionization energy
high electronegativity values
tend to gain electrons to form negative ions(anions) with larger radii
Metalloids
intermediate elements that display both metallic and nonmetallic properties
conduct electricity, but not as well as metals
shiny like metals but brittle like nonmetals
Noble Gases
group 18
unreactive
have completely filled valence electrons shells
stable electron configuration
H & He = duet rule
Octet Rule
atoms will gain, lose, or share electrons in order to obtain a stable octet of electrons
Hydrogen
doesn’t have properties similar to group 1(detached)
nonmetal
only element that can gain, lose, or share its one valence electrons to become stable
can form a +1 or -1 ion
Group 1(alkali metals) and Group 2(alkaline earth metals)
most reactive metals(group 1 > group 2, bottom of group > top of group)
reactive metal means they easily lose their electrons
can only be found in compounds in nature(free elements are produced by the electrolysis of the fused compounds)
Group 3-12: transition elements/metals
outermost d sublevels are being filled(non valence electrons)
typically hard solids with high melting points(except Hg)
transition elements typically have multiple oxidation(ionic) states(e- lost from more than one energy level)
less reactive than group 1 and group 2(copper, silver, gold are the least reactive)
transition elements typically form colored ions in solution
Group 14(carbon group)
structure = function
nonmetals that typically form network solids
carbon can have multiple forms in the same form(diamond vs. graphite)
allotropes
nonmetals that exist in two or more forms in the same phase. they have different chemical and physical properties because they have different structures(oxygen vs ozone and white vs red phosphorus)
Group 15 and Group 16
nitrogen and oxygen are both diatomic
BrINCl HOF
nitrogen contains a triple bond
oxygen contains a double bond
Group 17(halogens)
in a compound they are called halides
only group that contains all these phases of matter at room temperature
most reactive of the nonmetals
nonmetals react by gaining electrons
the top of the group is more reactive than the bottom of the group
can only be found in a combined state in nature(like group 1 and group 2)
Ion Formation for Groups
Group 1 - lose one electron, form a +1 ion
Group 2 - lose two electrons, form a +2 ion
Group 13 - lose three electrons, form a +3 ion
Group 16 - gain two electrons, form a -2 ion
Group 17 - gain one electron, form a -1 ion
number of e-s lost = number of e-s gained
atomic radius trend across a period
decreases
electronegativity trend across a period
increases
first ionization energy trend across a period
increases
metallic character(reactivity) trend across a period
decreases
nonmetallic character(reactivity) trend across a period
increases
atomic radius trend down a group
increases
electronegativity trend down a group
decreases
first ionization energy trend down a group
decreases
metallic character(reactivity) trend down a group
increases
nonmetallic character(reactivity) trend down a group
decreases
Why are periodic trends doing what they do down a group
more electron shells
Why are periodic trends doing what they do across a period?
more proton pull
how to find radius size
first, find what is positive and negative and sort accordingly
then, find the number of electrons