acid/bases

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44 Terms

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Define the following:

BRONSTED ACID
BRONSTED BASE
BRONSTED REACTION

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<p>label them according to the bronsted definition</p>

label them according to the bronsted definition

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<p>label them according to the bronsted definition</p>

label them according to the bronsted definition

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Lewis Base vs Lewis Acid

Quick Memory Trick:

“Base = Brings Electrons”
Lewis Base = Brings or Gives electron pair

<p><span data-name="check_mark_button" data-type="emoji">✅</span> <strong>Quick Memory Trick:</strong></p><figure data-type="blockquoteFigure"><div><blockquote><p><strong>“Base = Brings Electrons”</strong><br>Lewis Base = Brings or Gives electron pair</p></blockquote><figcaption></figcaption></div></figure><p></p>
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DIA

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<p>label it</p>

label it

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stronger KA means what?

stronger acid

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smaller pka means what?

stronger acid

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1 pka unit= …. change in acidity

10x change in acidity

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lower pkb means what?

stronger base

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higher strength of an acid means what in terms of pka and PKB?

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lower strength of an acid means what in terms of pka and PKB?

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<p>which side of the equation is preferred?</p>

which side of the equation is preferred?

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"Equilibrium favors the more stable side of the equation" means what

This means:

  • In a reaction, the system will shift toward the side with more stable molecules.

  • Stable = lower energy = favored.

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Strong acids/bases are blank stable + why

Weak acids/bases are more stable + why

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HA + B⁻ ⇌ A⁻ + HB

  • Left side: strong acid (HA) + strong base (B⁻) → less stable

  • Right side: weak acid (HB) + weak base (A⁻) → more stable 

  • WHERE WILL IT MOVE

So equilibrium shifts toward the weaker acid/base side (right).

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1. What makes an acid stronger?

Answer:
→ If its conjugate base is more stable.
Why?
Because a stable conjugate base is okay holding the negative charge, so the acid is happy to give away H⁺.

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2. How does conjugate base stability affect pKa?

Answer:
→ More stable base = lower pKa = stronger acid.
Why?
Stable base = acid gives H⁺ easily = stronger acid.

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3. What makes a conjugate base stable? Name 2 things.

Answer:
→ Resonance and electronegative atoms (like oxygen).
Why?
They spread or hold the negative charge better.

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6. What does a low pKa mean?

Answer:
→ Strong acid.
Why?
Low pKa = acid gives up H⁺ easily.

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7. What does a high pKa mean?

Answer:
→ Weak acid.
Why?
High pKa = acid wants to keep H⁺ = conjugate base is unstable.

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<p>label them acids and anions (stronger + weaker)</p>

label them acids and anions (stronger + weaker)

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ARIO?

atom

<p>atom </p><p></p>
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In the same row → more electronegative atom = is better at what holding blank charge? more/less base? weaker/stronger acid?

In the same row → more electronegative atom = better at holding negative charge = more stable base = stronger acid.

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groups vs periods on periodic table

Periodic Table Groups and Periods

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Bigger atom = better at holding negative charge = more stable conjugate base = stronger acid. but why?

🧠 Why does size matter?

  • A big atom spreads the negative charge out more (this is called polarizability).

  • A small atom holds the negative charge tightly in one spot → more unstable.

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<p></p>

D

<p>D</p>
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More stable anion → weaker base but why?

💡 Think about what a base does:

  • A base wants to grab a proton (H⁺).

  • If the conjugate base (anion) is very stable, it is happy just staying as it is.

  • So it doesn’t want to react or grab H⁺ → meaning it is a weak base.

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less stable anion --> stronger base why?

Because…

  • A less stable anion (negatively charged ion) is uncomfortable holding that negative charge.

  • To feel more stable, it wants to get rid of that negative charge.

  • The easiest way to do that is to grab a proton (H⁺).

  • A molecule that really wants to grab a proton is called a strong base.

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The inductive effect is
affected by

electronegativity,
2. # of electronegative
atoms
3. distance

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