5.9 Steady-State Approximation + 5.10 Multistep Reaction Energy Profile
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5 Terms
1
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How to determine a rate law expression if first elementary reaction is not rate limiting?
Make approximations (such as steady state)
2
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Why can’t an intermediate be included in the rate law of an overall reaction?
Because their initial concentrations are unknown
3
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What is the reversibility of a chemical reaction indicated by?
A double arrow
4
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What does the term equilibrium refer to?
A situation in which the rate of the forward reaction is equal to the rate of the reverse reaction
5
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What does knowledge of the energetics of each elementary reaction in a mechanism allow for?
Construction of an energy profile for the multistep reaction
Note 
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