5.9 Steady-State Approximation + 5.10 Multistep Reaction Energy Profile

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4 Terms

1
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How to determine a rate law expression if first elementary reaction is not rate limiting?

Make approximations (such as steady state)

2
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Why can’t an intermediate be included in the rate law of an overall reaction?

Because their initial concentrations are unknown

3
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What does the term equilibrium refer to?

A situation in which the rate of the forward reaction is equal to the rate of the reverse reaction

4
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What does knowledge of the energetics of each elementary reaction in a mechanism allow for?

Construction of an energy profile for the multistep reaction

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