aliphatic hydrocarbons
Long carbon chains (straight or cyclic) surrounded by hydrogen. They contain single, double, or triple bonds between carbons.
organic compound
Carbon-containing compounds.
Any of a large class of chemical compounds in which one or more atoms of carbon are covalently linked to atoms of other elements, most commonly hydrogen, oxygen, or nitrogen
inorganic compound
Does not contain C atoms.
Exceptions: CO2, carbides, carbonates, cyanides
carbon
The “element of life”: it bonds with a variety of elements in a variety of shapes, is an excellent building block due to strong bonds that are able to re-arrange themselves
alkanes
A class of hydrocarbon compounds that consist entirely of atoms of carbon and hydrogen bonded to one another by carbon-carbon and carbon-hydrogen single bonds.
- ane
Not soluble in water; soluble in non-polar solvents
Density is less than that of water
Boiling point increases as the size of the chain increases
London Forces!!
alkyl groups
Smaller carbon chains attached as branches to the parent.
methyl, ethyl, etc.
location numbers
The longest carbon chain (parent) is numbered to show on to which carbon a branch (alkyl group, functional group) is attached. If there are multiple branches on a parent chain, numbering starts on the end closest to the branch with the highest priority.
alkenes
A class of hydrocarbons with at least one carbon-to-carbon double bond.
- ene
Slightly more reactive than alkanes due to the double bonds
alkynes
A class of hydrocarbons which contain at least one carbon-carbon triple bond.
- yne
enynes
When there is a double bond and a triple bond in the same compound!
Number from the end closest to either the double or triple bond; if there’s a choice, the double bond gets priority (lowest #)!!
root - # - en - # - yne"
isomer
Molecules that have the same molecular formula, but their atoms are in different arrangement.
structural isomers
Molecules that have the SAME molecular formula, but their atoms are bonded together in a DIFFERENT sequence.
Physical properties, such as boiling points, vary, as do their shapes.
stereoisomers
Molecules that have the SAME molecular formula and their atoms are bonded together in the SAME sequence, but DIFFER in the 3D orientations of their atoms in space.
Alkenes have double bonds that are flat and rigid because their atoms cannot rotate around the double bond.
Two types: diastereomers and enantiomers
diastereomers
**** only for alkenes! ****
Each carbon atom involved in the DOUBLE BOND has DIFFERENT types of atoms or groups of atoms bonded to it.
The double bond prevents rotation around the carbon atoms, resulting in two separate orientations in space.
Two types of orientation: cis (D or Z) and trans (E)
cis
The two larger or smaller atoms or groups are on the SAME side of the double bond (above or below the bond plane).
trans
The two larger or smaller atoms or groups are on OPPOSITE sides of the double bond (one above and one below the bond plane).
enantiomers
**** only for a single carbon!! ****
Mirror images of each other around a SINGLE CARBON atom bonded to four DIFFERENT types of atoms or groups.
They are non-superimposable mirror images of each other (have different spatial arrangement).
For example, our hands!
alkyl halide hydrocarbons
Has at least one halogen side group.
Generally colourless and odourless compounds
They are hydrophobic in nature
Boiling point is higher than alkanes if the number of carbon atoms is the same in both
nitro hydrocarbons
Has at least one nitro side group.
cyclic hydrocarbons
General formula: CnH2n, represented by POLYGONS.
*** If you have one that is not the main chain, then you name it as a branch! The ending is changed to “yl”.**
aromatic hydrocarbons
Have a BENZENE ring, C6H6 - a six carbon, six hydrogen ring with alternating single & double bonds.
All six carbon-carbon bonds are intermediate in length between a single and double bond due to resonance (delocalized electrons are shared by all six carbon atoms).
benzene
C6H6, a six carbon, six hydrogen ring with alternating single & double bonds.
phenyl
***** If you have a benzene ring attached to a straight or cyclic hydrocarbon chain that is larger than the ring itself (more than 6 carbon atoms), the benzene ring is the side group and you name it as a branch!
alcohols
Contains a hydroxyl group (-OH) attached to a carbon chain (NOT hydroxide; the -OH group is covalently bonded rather than ionically bonded).
Higher boiling points than haloalkanes that remain associated with intermolecular hydrogen bonding
phenol
A hydroxyl group (-OH) attached to a benzene ring.
ethers
An oxygen atom bonded to two carbon atoms by single bonds.
“-oxy” ending
The boiling point is comparable to alkanes but much lower than that of alcohols of comparable molecular mass despite the polarity of the C-O bond
aldehydes
At least one H atom is attached to a carbonyl group (on the end of a carbon chain).
Have strong odors
Are polar compounds
Only dipole-dipole interactions (NO hydrogen bonding)
Low boiling points compared to amines and alcohols, higher than hydrocarbons
Soluble in water (not soluble in nonpolar compounds)
ketone
Two carbon groups are attached to a carbonyl group (in the middle of a chain).
Have pleasant odors
Are polar compounds
Only dipole-dipole interactions (NO hydrogen bonding)
Low boiling points compared to amines and alcohols, higher than hydrocarbons
Soluble in water (not soluble in nonpolar compounds)
carboxylic acids
**** TOP OF PRIORITY SHEET!!!!! **** → will ALWAYS be the parent group if they are present.
Contains a carboxyl group, which is a carbonyl group attached to a hydroxyl group (-COOH).
The common names use prefixes “form- and “acet-” for the first two carboxylic acids.
The carboxyl group contains three polar covalent bonds: C=O, C-O, and O-H; so they are polar
Have higher boiling points than other types of organic compounds (with the same molecular weight) because of hydrogen bonding
More soluble (!!!) in water than alcohols, ethers, aldehydes, and ketones because of stronger hydrogen bonding
Liquid forms have sharp and disagreeable odors
THEY TASTE SOUR (exist in pickle, lime, and lemon)
esters
**** FAVOURITE ON TESTS & EXAMS, LOTS OF REACTIONS!!!! ****
**** 2nd ON PRIORITY LIST ****
The H in the carboxyl group of a carboxylic acid is replaced with an alkyl group.
Give flowers and fruits their pleasant fragrances and flavours.
hydrolysis
Reaction with water; breaking a bond and adding the elements of water.
amines
Organic derivatives of ammonia (NH3), in which one or more alkyl, cycloalkyl, or aromatic groups replace hydrogen and bond to the nitrogen atom.
Classified as primary, secondary, and tertiary (similar to alcohols) → the number of carbon groups that are bound to the nitrogen atom.
The -NH2 group of a primary amine can be thought of as an “amino group” (a BRANCH).
State: tend to be gases for low molecular weight cases, many heavier ones are liquids are room temperature
Tend to exhibit strong odors, some have a “fishy” smell!
Boiling points are intermediate to those for alcohols and alkanes of similar molar mass; because of the presence of N-H bonds in primary + secondary, H-bonding is sometimes possible; however, because N is not as electronegative as O, the N-H bond is not as polar as an O-H bond (hence weaker H-bonding)
Tend to be water-soluble because of H-bonding interactions with water molecules; in fact, those with fewer than six carbon atoms are infinitely water-soluble
Water-solubility decreases as chain length increases and as the degree of N-substitution increases
amides
Possess a functional group that consists of a C=O (carbonyl) directly bonded to a nitrogen atom.
Classified as primary, secondary, and tertiary.
The simplest ones are liquids at room temperature, and all unbranched having 2 or more carbons on their C-chain side are solids
Secondary and tertiary have lower melting points, with tertiary amides having lower melting points than secondary amides (less opportunity for H-bonding).