Covalent Bonds and Molecular Compounds Review

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16 Terms

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Covalent bond

A bond formed by sharing electrons between atoms.

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Molecule

A group of atoms held together by covalent bonds.

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Bond length

The optimum distance between nuclei in a covalent bond where net attractive forces are maximized and the molecule is most stable.

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Diatomic molecule

Molecules made up of 2 of the same atom, whose formation increases stability due to overlap of orbitals.

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Seven diatomic elements

Nitrogen (N2), oxygen (O2), hydrogen (H2), fluorine (F2), chlorine (Cl2), bromine (Br2), and iodine (I2).

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Octet rule

The principle that compounds share enough electrons to complete eight valence electrons (s and p filled) around each atom.

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Molecular compounds

Compounds that consist of molecules rather than ions, typically formed by nonmetals sharing valence electrons.

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Multiple covalent bonds

Covalent bonds formed by sharing more than two electrons between atoms when single bonds are insufficient to satisfy the octet rule.

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Single bond

A covalent bond formed by sharing one electron pair, represented by a single line (e.g., H-H).

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Double bond

A covalent bond formed by sharing two electron pairs, represented by a double line (e.g., O=O).

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Triple bond

A covalent bond formed by sharing three electron pairs, represented by a triple line (e.g., N≡N).

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Coordinate Covalent Bond

A covalent bond that forms when both shared electrons are donated by the same atom.

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Polyatomic Ion

An ion where the number of protons and electrons are not equal, but the bonds between its constituent atoms are covalent.

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Ionic Compounds (characteristics)

Composed of ions (metals with nonmetals), crystalline solids, high melting/boiling points, conduct electricity when molten or dissolved, many are water-soluble.

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Molecular Compounds (characteristics)

Composed of molecules (nonmetals with nonmetals), gases, liquids, or low-melting-point solids, low melting/boiling points, do not conduct electricity, many are soluble in organic liquids.

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Intermolecular forces

Forces that exist between molecules, which determine the physical