Chem 2 lab final UF

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43 Terms

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Alpha

stopped by paper

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Beta

stopped by metal

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gamma

stopped by lead

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k

rate constant

<p>rate constant</p>
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zero order

[A] vs time

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first order

ln[A] vs time

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second order

1/[A] vs time

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range

maximum - minimum value

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percent error

experimental-actual/actual

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Beers law

explains the relationship between absorbance, at a given wavelength and concentration, A = εbc

<p>explains the relationship between absorbance, at a given wavelength and concentration, A = εbc</p>
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Dilution

the process of reducing the concentration of a solution by adding more solvent to it.

M1V1=M2V2

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Serial Dilution

stepwise dilution process

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Spectrophotometer

An instrument used to measure the intensity of light at different wavelengths in a sample.

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Transmittance

measure of the amount of light that passes through a substance or medium

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Red

650-750nm

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orange

580-650nm

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yellow

560-580nm

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green

490-560nm

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blue

430-490nm

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violet

400-430nm

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Equilibrium

The rates of forward and reverse reaction are equal

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Kc

equilibrium constant for reactions based on concentrations

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Kp

equilibrium constant for reactions based on partial pressures

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Le Chatelier's Principle

When a chemical system at equilibrium is disturbed, it returns to equilibrium by counteracting the disturbance

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Acid-base indicator

a weak organic acid whose color differs from that of its conjugate base

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Ksp

solubility product constant

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Titration

technique used to determine the concentration of a substance in a solution by reacting it with a known volume and concentration of another substance (titrant)

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Analyte

the substance in a solution whose concentration is being determined through titration

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Equivalence point

the point at which the two solutions used in a titration are present in chemically equivalent amounts

<p>the point at which the two solutions used in a titration are present in chemically equivalent amounts</p>
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Buffer region

A section of the titration curve where the pH changes gradually as acid or base is added

<p>A section of the titration curve where the pH changes gradually as acid or base is added</p>
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Calibration

Regular adjustments to tools to keep them accurate.

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Buffers

solutions that have a weak acid and its conjugate base, or vice versa.

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gel electrophoresis

technique for sorting molecules or fragments of molecules by length

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Cathode

Black, negative, samples are put here first

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Anode

Red, positive, samples travel here

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Entropy

A measure of disorder or randomness, S

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Gibbs free energy change

determines whether a reaction is spontaneous or requires energy. negative G=spontaneous

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Second law of thermodynamics

all spontaneous processes involved in increase in the entropy of the universe

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Galvanic cell

An electrochemical cell powered by a SPONTANEOUS redox reaction that produces an electric current flow; also called a voltaic cell.

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Electrolytic cell

Uses an electrical current to drive a non spontaneous reaction

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concentration cell

a galvanic cell in which both compartments contain the same components, but at different concentrations

<p>a galvanic cell in which both compartments contain the same components, but at different concentrations</p>
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Complex ion

Central metal cation bonded to ligands

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Isomers

compounds with the same molecular formula but different structures and properties

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