Geometry and Hybridization

Bent with 4 electron groups (bond angles)

<109.5 degrees

bent with 4 electron groups (hybridization)

sp^3

H₂O (molecular geometry)

bent

tetrahedral (bond angles)

109.5 degrees

tetrahedral (hybridization)

sp^3

CH₄ (molecular geometry)

tetrahedral

Linear (bond angles)

180 degrees

Linear (hybridization)

sp

CO₂ (molecular geometry)

linear

trigonal pyramidal (bond angles)

<109.5 degrees

trigonal pyramidal (hybridization)

sp^3

trigonal pyramidal (electron geometry)

tetrahedral

NH₃ (molecular geometry)

trigonal pyramidal

trigonal planar (bond angles)

120 degrees

trigonal planar (hybridization)

sp^2

BF₃ (molecular geometry)

trigonal planar

trigonal bipyramidal (bond angles)

90 degrees & 120 degrees

trigonal bipyramidal (hybridization)

sp^3d

AsFCl₄ (molecular geometry)

trigonal bipyramidal

octahedral (bond angles)

90 degrees

octahedral (hybridization)

sp^3d^2

SF₆ (molecular geometry)

octahedral

see-saw (bond angles)

<90 degrees & <120 degrees

see-saw (hybridization)

sp^3d

see-saw (electron geometry)

trigonal bipyramidal

SF₄ (molecular geometry)

see-saw

T-shape (bond angles)

<90 degrees

T-shape (hybridization)

sp^3d

T-shape (electron geometry)

trigonal bipyramidal

ClF₃ (molecular geometry)

T-shape

square pyramidal (bond angles)

<90 degrees

square pyramidal (hybridization)

sp^3d^2

square pyramidal (electron geometry)

octahedral

BrF₅ (molecular geometry)

square pyramidal

square planar (bond angles)

90 degrees

square planar (hybridization)

sp^3d^2

square planar (electron geometry)

octahedral

XeF₄ (molecular geometry)

square planar