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What is the leading hypothesis for the origin of life on Earth
Chemical evolution
explain chemical evolution
simple atoms resulted in more complex carbon containing molecules resulting in a molecule that could replicate itself, as replication occurred so did natural selection
four atoms that make up 96% of matter
hydrogen carbon nitrogen and oxygen
non polar covalent bonds and symmetry
symmetrical
where did chemical evolution likely originate
in water based environment, life is based on water
each proton and neyutron are similar in mas and weigh has a mass of..
one dalton
atoms with the same atomic number have what in common
same chemical properties and belong to same element
the number of unpaired electrons is called the
valence of an atom
what do valence electrons contribute to
the chemical bonding
when are atoms most stable
when their outer shell is full by the formation of chemical bonds
molecules
held by covalent bonds
compund
atoms of different elements are held together and may not be shared eq
electronegativity
strength in which they attract electrons to their nuclei
where on the periodic table is there a higher electronegativity
up and right
what’s electronegativity determined by
the distance of the valence shell from the nucleus, and number of protons in the nucleus
two types of covalent bonds and what they are
non polar covalent: equal sharing (c-h)
polar : un equal sharing (o-h)
ionic bonds
electrons are transferred by one atom to another because it gives the resulting atoms a valence shell
solute and solvent
solvent: water
solute: salt
what makes water such a good solvent
the partial neg charge, the hydrogen have partial positive, the charges are at opposite ends. therefore, partial neg attracts partial positive hydrogen which creates hydrogen bonds
cation v anion
c: loses to become positive
a: gains to become negative
hydrogen bonds
when the partial negative of an oxygen attracts the partial positive of an hydrogen— weak electrical attractions
hydrophilic vs hydrophobic and whether they are polar or not
philic yes they are polar
phobic no they are non polar
waters properties
cohesion
adhesion
denser as a liquid than solid
absorbs large amount of eng
cohesion
bind to itself via hydrogen bonding to create factors like surface tension
adhesion
water binds to other such as glass or plastic
more dense as liquid
most substances shrink while becoming slid but water expands and is more dense as a liquid than it is as a solid creating a crystal structure hence why ice floats on water
water molecules dissociate into
hydrogen and hydroxide happening at both directions equally (equilibrium), as protons don’t exist alone it allows for the creation of hydronium ions
what is produced by water molecule disassociation
hydronium ions
acids
give up protons which raises hydronium (adding an ion raises the proton concentration)
bases
acquire protons during them rxn and lower hydronium concentration
buffers
minimize change in pH and sustain homeostasis
energy
capacity to do work or supply heat
kinetic v potential eng
potential, stored potential to do work
kinetic, active energy of movement
in molecules what is potential eng related to
position of shared e in covalent bonds
chemical eng
molecules potential to become stronger
what happens when u go polar to non polar
potetuak energy increases
position of share e from atom nuclei
closer to one or both : strong (ionic)
shifted far from atom nuclei long an weak bonds
thermal eng
kinetic energy of molecular motion
heat
measure of thermal energy being transferred between two objectsf
first law of thermodynamics
energy is conserved, it cannot be created or destroyed just transferred or transformed
chemical spontaneously rxn
they happen without external influence
ex: ball roll down hill
what direction do physical and chemical processes proceed in
the result that results in lower potential eng and increased disorder
spontaneity of reaction determined by
product are less ordered than reactants(entropy increases)
products have lower potential eng than reactants
second law of thermodynamics
entropy always increases
carbon
super versatile - 4 e allowing it to bond multiple types
org compounds
molecules that contain carbon bonded to other elements
chlorine has a charge of -2 what does that indicate
gains two electrons
what makes a solution
solute dissolved in a solvent
solute is
what gets dissolved
solvent is
what surround the solute
when a substance is dissolved in smth like water
they are more likely to react as water os a good solvent
descrive water
it is polar oxygen has partial neg, hydrogen has partial positive allowing hydrogen bonding
hydrogen bonds only in reference to water?
no, they can form between hydrogen and any other polar molecule
hydrophilic “water loving” descriptiom
they are ions and polar molecules present in solution in which are able to interact w partial charges
hydrogen bonding makes what possible
makes it possible for any polar molecule to dissolve in water
hydrophobic “water fearing”
they are uncharged molecules that do not dissolve in water
acids have a ph of
less than 7
bases have a ph of
greater than 7
in molecules what happens if shared electrons are far from nuclei
bonds are long and weak
in a molecule what happens if the electrons are shifted closer to one or both nuclei
the bond becomes shorter and stronger
2 q that are fundamental in learning how simple substances could have evolved yo such complex structures
what is the physical structure of hydrogen, carbon, nitrogen and oxygen found in cells
what is the structure of simple blocks like h20 and c02 that served as building blocks
how are atomic no, and mass organize
atomic number: subscript left
mass: left but up
carbon 14 with 8 neutrons
represents a radioactive isotope in which the nucleus will decay and release energy in the form of radiation
what happens to c14 when it decays (n and p)
neutrons change to protons making it a different element
define ion
atom or molecule that carries a full charge rather than a partial charge that come from polar covalent
methane
CH4 commonly found in gas
atoms w more than one unpaired electron
can form double or triple bonds
double bond
2 pairs of e shared whilst triple bond is 3 pair of e is shared
molecular formulas
indicate numbers and types of atoms in a molecule
structural formula
indicate which molecule are bonded tg (dingle double and triple),,, also indicates geometry in 2 dimensions
how much volume in a cell is water
75%
chemical reaction equations
reactant left and result right,
water molecule chemical exp
disassociation
dynamic stable state as chemical run
chemical equilibrium
molarity
number of moles of the solute present per litre
endothermic rxn
thermal energy is absorbed by system during process
exothermic run
release of thermal energy to the environment
prebiotic soup model
certain molecules synthesized from atmosphere via meteorites
surface metabolism model
dissolved gasses come in contact with minerals lining walls of deep sea vents